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Corrosion behavior of three Ag–50Cu alloys prepared by different processes in NaCl solutions 被引量:4

Corrosion behavior of three Ag–50Cu alloys prepared by different processes in NaCl solutions
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摘要 Corrosion behavior of two nanocrystalline bulk Ag–50Cu alloys and one coarse-grained counterpart prepared by liquid-phase reduction(LPR), mechanical alloying(MA) and powder metallurgy(PM) methods,respectively, were investigated in Na Cl solutions. They were finished by means of PARM273 A and M5210 electrochemical apparatus through potentiodynamic polarization method and electrochemical impedance spectroscopy(EIS) technique. The results show that corrosion rates of three Ag–50Cu alloys increase with the increment of Na Cl solution concentrations. Corrosion rates of LPRAg–50Cu alloy are a little higher than those of PMAg–50Cu alloy,but evidently lower than those of MAAg–50Cu alloy. The difference in corrosion rates is attributed to the large reduction in the grain size and homogeneous microstructure of nanocrystalline alloys. Passive current densities decrease and afterward increase for PMAg–50Cu alloy,decrease for MAAg–50Cu alloy, and increase for LPRAg–50Cu alloy with the increment of Na Cl solution concentrations. After the grain sizes are refined, passive current densities become lower. Corrosion behavior of two nanocrystalline bulk Ag–50Cu alloys and one coarse-grained counterpart prepared by liquid-phase reduction(LPR), mechanical alloying(MA) and powder metallurgy(PM) methods,respectively, were investigated in Na Cl solutions. They were finished by means of PARM273 A and M5210 electrochemical apparatus through potentiodynamic polarization method and electrochemical impedance spectroscopy(EIS) technique. The results show that corrosion rates of three Ag–50Cu alloys increase with the increment of Na Cl solution concentrations. Corrosion rates of LPRAg–50Cu alloy are a little higher than those of PMAg–50Cu alloy,but evidently lower than those of MAAg–50Cu alloy. The difference in corrosion rates is attributed to the large reduction in the grain size and homogeneous microstructure of nanocrystalline alloys. Passive current densities decrease and afterward increase for PMAg–50Cu alloy,decrease for MAAg–50Cu alloy, and increase for LPRAg–50Cu alloy with the increment of Na Cl solution concentrations. After the grain sizes are refined, passive current densities become lower.
出处 《Rare Metals》 SCIE EI CAS CSCD 2017年第1期61-68,共8页 稀有金属(英文版)
基金 financially supported by the National Natural Science Foundation of China (Nos. 51271127 and 51501118)
关键词 Copper alloys Corrosion Corrosion rate Corrosive effects Electrochemical corrosion Electrochemical impedance spectroscopy ELECTROCHEMISTRY Grain size and shape Mechanical alloying Nanocrystals Powder metallurgy Reduction Silver Silver alloys Copper alloys Corrosion Corrosion rate Corrosive effects Electrochemical corrosion Electrochemical impedance spectroscopy Electrochemistry Grain size and shape Mechanical alloying Nanocrystals Powder metallurgy Reduction Silver Silver alloys
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