摘要
自制X值不同的Ti_(0.7)Zr_(0.3)(Cr_(1-x)V_x)_2合金,采用XRD和SEM对其成分及组织进行分析,同时利用Sieverts仪器测量结合贮氢量和贮氢密度数学计算模型,绘制合金的吸氢活化性能和压力-浓度-温度曲线。结果表明,Ti_(0.7)Zr_(0.3)(Cr_(1-x)V_x)_2合金为复杂的多相组织,由Laves相和不同晶格常数的bcc固溶相组成;合金具有较好的活化性能和抗氧化性能;随着V元素含量的增加,合金的贮氢含量增加,放氢含量减小。
The Ti0.7Zr0.3(Cr1-xVx)2 alloy was developed, and the composition and microstructure were analyzed using XRD and SEM. Meanwhile, the Sieverts apparatus was used to measure the alloy hydrogen activation absorption performance and pressure-temperature-concentration curve. The results show that the crystal structure of the Ti0.7Zr0.3(Cr1-xVx)2 belongs to a complicated muff-phase structure, which are composed of two Laves phase and some bee solid solution phase with different lattice constants; these alloy have good activation properties and oxidation resistances; with the increase of V element content, the hydrogen storage ability of the alloy increases.
作者
杨凯
高俊明
李浩
YANG Kai GAO Junming LI Hao(Hebei Engineering and Technical College, Cangzhou 061001, China)
出处
《铸造技术》
CAS
北大核心
2017年第3期541-543,共3页
Foundry Technology
关键词
多相组织
活化性能
抗氧化性能
储氢
polyphase structure
activation properties
oxidation resistance
hydrogen storage