期刊文献+

两种共扩链剂对水性聚氨酯分散液性能的影响

Effects of Two Co-Chain Extenders on Properties of Waterborne Polyurethane Dispersions
下载PDF
导出
摘要 以3,6-二氧杂-1,8-辛烷二硫醇(BOODT)、乙二胺(EDA)为二羟甲基丙酸(DMPA)的共扩链剂分别制备了两种水性聚氨酯分散液WPUS和WPUN。通过红外光谱(FT-IR)对两种水性聚氨酯结构进行了表征,同时探讨了这两种扩链剂对分散液稳定性及聚氨酯胶膜热稳定性、吸水率、力学性能的影响。结果表明,WPUS的贮存稳定性较WPUN的好,WPUS膜的热稳定性较WPUN膜好,WPUS膜的吸水率及拉伸强度低于WPUN膜的,而其断裂伸长率及拉伸剪切强度高于WPUN膜的。 Two series of waterborne polyurethane dispersions were synthesized by different co-chain extenders of dimethylpropionic acid, including 3,6-dioxa-1, 8-octanedithiol ( BOODT) and ethylene diamine (EDA). The structure of anionic waterborne polyurethane was characterized by Fourier transform infrared spectroscopy ( FT1R). The effects of chain extenders on the stability of dispersions,the thermal stability,water resistance and mechanical properties of polyurethane films were studied. The results showed that the waterborne polyurethane dispersion syn-thesized by BOODT as chain extender (WPUS) had better stability than the waterborne polyurethane dispersion synthesized by EDA as chain extender(WPUN). WPUS films had better thermal stability than WPUN films. The water resistance and tensile strength of WPUS films were worse than those of WPUN films,while their elongation at break and tensile shear strength were better than those of WPUN films.
出处 《聚氨酯工业》 北大核心 2017年第2期20-23,共4页 Polyurethane Industry
关键词 二硫醇扩链剂 水性聚氨酯 分散液 dithiol chain extender waterborne polyurethane dispersion
  • 相关文献

参考文献4

二级参考文献29

  • 1曹堃,吴建芬,孙建中,顾培韵.水性聚氨酯研究进展[J].高分子通报,1994(3):156-161. 被引量:49
  • 2张涛,李树材.环境友好型水性聚氨酯材料耐水性的研究[J].聚氨酯工业,2006,21(1):20-23. 被引量:2
  • 3南博华,郑水蓉,孙曼灵,王红丽,郑高峰.扩链剂对单组分阴离子型水性聚氨酯涂料性能的影响[J].涂料工业,2006,36(6):20-23. 被引量:7
  • 4朱冰,汤克勇,王全杰.正丁胺为扩链剂合成水性聚氨酯皮革涂饰剂[J].高分子材料科学与工程,2007,23(3):88-91. 被引量:8
  • 5Tobolskyav. Properties of linear elastomeric polyurethanes [ J ]. J Polym Sci, 1996, 10:1837-1844.
  • 6Madbouly S A, Otaigbe J U. Kinetic analysis of fractal gel formation in waterborne polyurethanedispersions undergoing high deformation flows[J]. Macromoleeules, 2006, 39:4144-4151.
  • 7Nanda A K, Wicks D A. The influence of the ionic concentration, concentration of the polymer, degree of neutralization and chain ex- tension on aqueous polyurethanedispersions prepared by the acetone process[J]. Polymer, 2006, 47:1805 - 1811.
  • 8Yen M S, Tsai P Y, Hong P D. The solution properties and mem- brane properties of polydimethylsiloxane waterborne polyurethane blended with the waterborne polyurethanes of various kinds of soft segments[ J]. Colloid Surf A, 2006, 279 : 1 - 9.
  • 9Furukawa M, Hamada Y, Kojio K. Aggregation structure and me- chanical properties of functionally graded polyurethane elastomers [J]. J Polym Sci. Part B: Polym Phys, 2003, 41 : 2355 -2364.
  • 10Aznar A C, Pardini O R, Amalvya J I. Glossy topcoat exterior paint formulations using water-based polyurethane/acrylic hybrid binders [J]. Pro Org Coat, 2006, 55:43 -49.

共引文献19

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部