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A Pair of 3D Homochiral Coordination Polymers with Open Channels Constructed by Lactic Acid Derivative Ligands and In-situ Formed Anions 被引量:1

A Pair of 3D Homochiral Coordination Polymers with Open Channels Constructed by Lactic Acid Derivative Ligands and In-situ Formed Anions
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摘要 With the help of in-situ formed CH_3COO- anion, a pair of 3D homochiral coordination polymers with open channels were constructed by the assembly of lactic acid derivative ligands, 1.4-DIB ligands and Cd(II) ions, namely [Cd3((R)-CIA)2(CH3CO2)_2(1.4-DIB)2(H2O)2]·x(Guest)(1-D) and [Cd3((S)-CIA)2(CH3CO2)2(1.4-DIB)2(H2O)2]·x(Guest)(1-L). They contain 1D interesting ladder-like Cd-(R)-CIA(3-) chains and exhibit SHG-active behavior and photoluminescent property. With the help of in-situ formed CH_3COO- anion, a pair of 3D homochiral coordination polymers with open channels were constructed by the assembly of lactic acid derivative ligands, 1.4-DIB ligands and Cd(II) ions, namely [Cd3((R)-CIA)2(CH3CO2)_2(1.4-DIB)2(H2O)2]·x(Guest)(1-D) and [Cd3((S)-CIA)2(CH3CO2)2(1.4-DIB)2(H2O)2]·x(Guest)(1-L). They contain 1D interesting ladder-like Cd-(R)-CIA(3-) chains and exhibit SHG-active behavior and photoluminescent property.
出处 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2017年第4期671-678,共8页 结构化学(英文)
基金 supported by the Natural Science Foundation of Guizhou Province(20122344) 125 program of Guizhou Education Department(2012015) the Doctoral Scientific Fund of Zunyi Normal College(2012BSJJ12)
关键词 homochiral coordination polymers lactic acid derivative ligand open channel SHG-active behavior photoluminescent property homochiral coordination polymers lactic acid derivative ligand open channel SHG-active behavior photoluminescent property
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