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有机氢供体重整制氢在纤维素降解制生物基化学品中的研究进展 被引量:1

Research progress in biomass hydrogenolysis to chemicals coupled with reforming steam of organic hydrogen donors
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摘要 以有机氢供体为氢源代替高纯H_2用于纤维素降解制生物基化学品是当前纤维素氢解的一种具有很好应用前景的新方法。综述了3种低碳醇甲醇、乙醇、异丙醇和小分子富氢酸这几类氢供体应用于纤维素氢解制备化学品及其机理的研究进展,对比了以醇类作为有机氢供体的绿色氢解和常规氢解(以高纯氢为氢源)的优缺点,并对有机氢供体重整在纤维素氢解制备生物基化学品的应用前景进行展望。 It is a new and promising strategy that cellulose hydrogenolysis to bio-based chemicals coupled with the reforming steam reaction of organic hydrogen donors rather than free H2. Four types of hydrogen donors including bio-methanol,bio-ethanol isopropanol and formate for cellulose hydrogenolysis to chemicals were summarized. Moreover,the merits and drawbacks of hydrogenolysis based organic hydrogen donor and normal hydrogenolysis was demonstrated by practical examples. Eventually,the application of cellulose hydrogenolysis to bio-based chemicals coupled with the reforming steam reaction of organic hydrogen donors were counseled.
出处 《应用化工》 CAS CSCD 北大核心 2016年第12期2360-2365,共6页 Applied Chemical Industry
基金 浙江省教育厅科研项目(Y20112088) 浙江省科技计划项目(2011R09028-10)
关键词 氢供体 重整 生物质 氢解 化学品 hydrogen donor steam reforming biomass hydrogenolysis bio-based chemicals
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  • 1杜贤龙,刘永梅,王建强,曹勇,范康年.碳纳米管担载纳米Ir催化生物质基乙酰丙酸合成γ-戊内酯(英文)[J].催化学报,2013,34(5):993-100. 被引量:16
  • 2周立坤,庞纪峰,王爱琴,张涛.组合催化剂WO3+RaneyNi上高效转化菊芋秸秆制乙二醇(英文)[J].催化学报,2013,34(11):2041-2046. 被引量:9
  • 3刘楚圣.异丙醇气相催化脱氢制丙酮的研究[J].精细石油化工,1996,13(3):26-28. 被引量:3
  • 4浙江大学.一种还原芳磺酸或其衍生物制备相应硫酚的方法:中国,200810121533.X[P].2008-10-16.
  • 5THOMAS C L. Hydrocarbon Reactions in the Pres-ence of Cracking Catalysts. II. H Transfer[J]. AmChem Soc,1944,66(9): 1586-1589.
  • 6FRANCISCO A,PAOLA R,MIIGUEL Y. NickelNanoparticles in Hydrogen Transfer Reaction [J],Accounts of Chem Res,2011,44(5) : 379-391.
  • 7ADOLFSSON H. Organocatalytic Hydrogen Trans-fers: A New Concept in Asymmetric Hydrogenations[J]. Angewandte Chem, 2005 ,44(22) : 3340-3342.
  • 8MIKHALENKO N N, KHRAPOVA E V,GRYAZNOV V. Effect of Hydrogen TransferThrough a Membrane Catalyst from a Palladium-Ru-theniun Alloy on the Rates of Isopropanol Dehydro-genation and Cyclopentadiene Hydrogenation [J].Neftekhimiyaa978,18(3): 354-357.
  • 9DHAKSHINAMOORTHY A, PITCHUMANI K.Clay Entrapped Nickel Nanoparticles as Efficient andRecyclable Catslysts for Hydrogenation of Olefins[J]. Tetrahedron Lett,2008?49(18) : 1818-1823.
  • 10KOSJEK B, TELLERS D M, BIBA M, et al. Bio-cayalytic and Chemocatalytic Approaches to the High-ly Stereoselective 1,2-Reduction of an a?/?-Unsaturat-ed Alcohols on Au Supported Catalysts[J]. Catal To-day,2007,122(3-4) :341-351.

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