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PdSn/Fe_3O_4-C催化剂的制备及其对乙醇氧化的电催化性能

Preparation of PdSn/Fe_3O_4-C Catalysts and Their Electro-catalytic Activities for The Oxidation of Ethyl Alcohol
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摘要 采用包覆法制得不同Fe_3O_4含量的载体Fe_3O_4-C(1),以PdCl_2和SnCl_2·2H_2O为金属前驱体,采用化学还原法制得催化剂(PdSn/1),其结构和性能经TEM,XRD和EDS表征。采用循环伏安法(CV)、计时电流法(CA)和交流阻抗(EIS)技术研究了PdSn/1在碱性条件下对乙醇氧化的电催化性能。结果表明:PdSn/1(5%)表现出较高的电催化活性,乙醇氧化的峰电流密度达到147 mA·cm^(-2);相比于Pd/C,PdSn/1(5%)对乙醇氧化反应的电荷转移阻力也有大幅度下降。 Fe3O4-C (1) with different quantities of Fe3O4 were prepared by coating method. The nano-catalysts(PdSn/1) were prepared by reduction method, using PdCl2 and SnCl2 ·2H2O as metal precursor. The structures and properties were characterized by TEM, XRD and EDS. The electroactiv- ity of PdSn/1 for ethanol oxidation in alkaline media were studied by cyclic voltammetry (CV) , chrono- amperometry(CA) and electrochemical impedance spectra (EIS). The results showed that PdSn/1 (5 % ) showed the rent density of 147 transfer resistance highest catalytic activity for ethanol oxidation wuth the ethanol oxidation peak cur- mA · cm-2 Compared with Pd/C, PdSn/1(5% ) presents the much lower charge for ethanol oxidation reaction.
作者 邹涛 易清风 张媛媛 向柏霖 周秀林 ZOU Tao YI Qing-feng ZHANG Yuan-yuan XIANG Bai-lin ZHOU Xiu-lin(School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan 411201, China Chemistry and Material Engineering Department, Huaihua University, Huaihua 418000, China)
出处 《合成化学》 CAS CSCD 2017年第6期480-486,共7页 Chinese Journal of Synthetic Chemistry
基金 国家自然科学基金资助项目(21376070) 湖南省研究生科研创新项目(CX2016B567)
关键词 钯催化剂 乙醇氧化 钯锡 燃料电池 制备 电催化性能 palladium catalyst ethanol oxidation palladium tin fuel cell preparation electro-cata- lytic activity
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