摘要
通过简单的共沉淀法制备掺杂不同碳管含量的Ag_3PO_4/MWCNTs复合光催化材料,并对样品进行XRD、SEM、FT-IR、UV-vis等表征。以300 W氙灯模拟太阳光,通过光催化材料对甲基橙的降解来评价光催化材料对印染废水的催化效果。结果表明:PVP的存在使得制备的Ag_3PO_4颗粒表面光滑、结晶性好、尺寸较小(200~300 nm);经过混酸改性后增加了大量的带有羧基基团的碳管,均匀地分布在Ag_3PO_4颗粒表面,与其形成了很好的复合;合成的复合材料较纯Ag_3PO_4具有更加优异的光催化活性,当碳管质量分数为3.6%时催化效果最好。最后,对所制备材料的光催化机理进行了分析。
Novel Ag3PO4/MWCNTs composite photocatalysts with different CNTs contents have been successfully synthesized by a simple precipitation process and characterized by XRD,SEM,UV-vis and FT-IR. The photocatalytic performance of the as-prepared photocatalysts in the degradation of dye wastewater was tested using methyl orange（ MO） as a representative dye under simulated visible light irradiation by a 300 WXe lamp. The results showed that Ag3PO4 nanoparticles exhibit high crystallinity and smaller size（ 200-300 nm） when prepared in the presence of PVP. A mixed acid treatment results in the formation of a large number carboxyl groups on the surface of MWCNTs,which promotes the coupling with Ag3PO4 nanoparticles. Ag3PO4/3. 6% MWCNTs displayed a higher photocatalytic activity than pure Ag3PO4 and other composites contained different CNTs contents. The mechanism for the photocatalytic degradation of MO is discussed at the end of this paper.
出处
《北京化工大学学报（自然科学版）》
CAS
CSCD
北大核心
2017年第4期69-75,共7页
Journal of Beijing University of Chemical Technology(Natural Science Edition)
基金
陕西省自然科学基金(2015JQ5173)
中央高校基本科研业务费(310829161016)
关键词
光催化材料
印染废水
甲基橙
磷酸银
photocatalyst
dye wastewater
methyl orange
silver phosphate
