摘要
以二苯甲酮肟为基础底物,在hp20_ss新型固体超强酸催化作用下,经Beckmann重排得到酰胺,并研究了二苯甲酮肟苯环上吸电子基团对Beckmann重排取向的影响,对其可能的机理进行了探讨。
This paper is based on diphenylketone oxime,which is rearranged by Beckmann under the catalytic action ofhp20_ss new solid superacid. In this paper,the influence of the adsorption electron group on the rearrangement of Beckmannwas studied, and the possible mechanism was discussed.
作者
胡靖雯
胡辉杰
陈春蕾
陈茗
赵金晶
鲁倩倩
HU Jing-wen;HU Hui-jie;CHEN Chun-lei;CHEN Ming;ZHAO Jin-jing;LU Qian-qian(College of Chemical Engineering, Shaoxing College of Letters and Sciences, Shaoxing 312000, China)ct:)
出处
《安徽化工》
CAS
2017年第6期66-69,共4页
Anhui Chemical Industry