摘要
以1,1'-二茂铁双甲酰肼与3-氯-4-羟基苯甲醛为原料合成了含有3-氯-4-羟基亚苄基的二茂铁双酰腙化合物。通过UV、IR、1H NMR、HR MS、HPLC等手段对化合物结构进行分析表征,测试其电化学性能。结果表明:二茂铁双酰腙的化合物的循环伏安曲线中存在铁原子的得失电子(Fc^+/Fc)的氧化还原峰,且在高电位区呈现出不可逆氧化过程。
A ferrocenyl hydrazone compound containing 3-chloro-4-hydroxybenzylidene was successfully synthesized using 1,1＇-ferrocenium bishydrazide and 5-chlorosalicylaldehyde as raw materials. The structure and the electrochemical performance of these compounds were investigated using UV, IR,~1H NMR, HR MS and HPLC. The redox peak of the cyclic voltammetry curves indicated that the compound existed Fc~＋/Fc electric couple. It was noted that irreversible oxidation peaks appeared in the high potential region.
作者
李宇飞
刘亚坚
孟宪娇
王世珍
冯彦梅
杨云峰
LI Yu-fei;LIU Ya-jian;MENG Xian-jiao;WANG Shi-zhen;FENG Yan-mei;YANG Yun-fen(North University of China, School of Science, Taiyuan 030051,China;North University of China, School of Chemical Engineering and Techndogy, Taiyuan 030051, China)
出处
《精细化工中间体》
CAS
2017年第5期32-34,42,共4页
Fine Chemical Intermediates
关键词
二茂铁
酰腙
循环伏安法
ferrocene
acylhydrazone
cyclic vohammetry
