摘要
Via the strategy of charge balance,one new pillared layered metal-organic framework [Zn2（TNB）（2-nim）]（H3TNB = 4,4？,4？？-nitrilotribenzoicacid,2-nim = 2-nitroimidazole）（1） was successfully synthesized based on mixed ligands,where binuclear [Zn2（CO2）3]~＋ cluster-based cationic layers [Zn2（TNB）]~＋ are connected by deprotonated 2-nitroimidazole.Meanwhile,CO2 adsorption bahaviors and luminescent property of compound 1 were investigated.
Via the strategy of charge balance,one new pillared layered metal-organic framework [Zn2（TNB）（2-nim）]（H3TNB = 4,4？,4？？-nitrilotribenzoicacid,2-nim = 2-nitroimidazole）（1） was successfully synthesized based on mixed ligands,where binuclear [Zn2（CO2）3]~＋ cluster-based cationic layers [Zn2（TNB）]~＋ are connected by deprotonated 2-nitroimidazole.Meanwhile,CO2 adsorption bahaviors and luminescent property of compound 1 were investigated.
基金
financially supported by the National Natural Science Foundation of China(No.21601080)
the Key Scientific Research Projects of Higher Education of He'nan Province(16A150016)
