摘要
研究了Cu-Be-Co-Zr合金480℃恒温时效条件下的时效析出动力学。根据导电率与析出相体积分数的关系,计算了Cu-Be-Co-Z合金不同时效时间(0,30,60,120,180,240,360,480,600 min)对应的析出相转变比率,建立了Cu-Be-Co-Zr合金480℃时效条件下的析出相变动力学方程和导电率方程,并在此基础上绘制了等温转变动力学S曲线;采用固态热分解反应机理的积分方程,揭示了Cu-Be-Co-Zr合金时效析出转变机制为受扩散控制的反应机理。
The phase transformation kinetics of Cu-Be-Co-Zr alloy during aging treatment was investigated. Based on the relationship between electrical conductivity and volume fraction of precipitates, the phase transformation ratios of Cu-Be-Co-Zr alloy aged at 480 ℃ for different holding time（0, 30, 60, 120, 180, 240, 360, 480, and 600 min） were calculated. The kinetics equation of phase transformation and the electrical conductivity equation were derived. The isothermal transformation kinetics S-curves of Cu-Be-Co-Zr alloy was drawn. By the integral equation of solid thermal decomposition reaction mechanism, the phase transformation mechanism of Cu-Be-Co-Zr alloy is controlled by three dimensions of diffusion.
作者
周延军
宋克兴
米绪军
刘勇
杨少丹
李周
Zhou Yanjun;Song Kexing;Mi Xujun;Liu Yong;Yang Shaodan;Li Zhou(Henan University of Science and Technology, Luoyang 471023, China;General Research Institute for Nonferrous Metals, Beijing 100088, China;Central South University, Changsha 410006, China)
出处
《稀有金属材料与工程》
SCIE
EI
CAS
CSCD
北大核心
2018年第4期1096-1099,共4页
Rare Metal Materials and Engineering
基金
National Key Research and Development Program of China(2016YFB0301400)
State Key Program of National Natural Science Foundation of China(U1502274)
Innovation Scientists and Technicians Troop Construction Projects of Henan Province(C20150014)
Program for Innovation Research Team(in Science and Technology)in University of Henan Province(14IRTSTHN007)
