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MA/AMPS/APEG防垢剂的合成以及性能评价 被引量:1

SYNTHESIS AND PERFORMANCE EVALUATION OF MA/AMPS/APEG AS SCALE INHIBITOR FOR CALCIUM CARBONATE
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摘要 为解决油田采出水管道系统结垢问题,通过对防垢剂作用机理和分子结构的设计与分析,以马来酸酐(MA)、2-丙烯酰胺基-2-甲基-1-丙磺酸(AMPS)、烯丙基聚乙二醇1000(APEG-1000)合成聚合物MA/AMPS/APEG-1000防垢剂。根据油田用防垢剂评价标准,测定单因素合成防垢剂的防垢率,以此确定合成最佳条件:反应单体配比n(MA)∶n(AMPS)∶n(APEG-1000)=2∶1∶0.002,引发剂浓度3.5%,反应时间6h,反应温度85℃,单体总质量分数20%。由红外光谱(FTIR)分子结构表征结果表明,合成的样品与预期结构一致;凝胶色谱(GPC)相对分子质量测定MA/AMPS/APEG-1000的M_w=3145,为低相对分子质量聚合物;防垢性能实验结果表明,当钙离子浓度较高时,碳酸钙微晶会包裹聚合物分子,弱化防垢性能,当钙离子浓度合适时,MA/AMPS/APEG-1000防垢剂对碳酸钙有良好的防垢效果。 Aimed at solve the scaling problem of the produced water pipeline system in oilfield.Based on the inhibition mechanism and design and analysis of molecular structure,oligomeric carboxylic inhibitor AM/AMPS/APEG was synthesized with maleic anhydride(MA),2-acrylamide-2-methyl-1-propanesulfonic acid(AMPS),allylpolyethylene glycol 1000(APEG-1000)for calcium carbonate scale.According to the oilfield scale inhibitor evaluation standard,the inhibition rate of the single factor synthetic scale inhibitor was determined to choose the optimal synthesis conditions:the molar ratio of reaction monomer is 2∶1∶0.002,the initiator concentration is 4.0%,the reaction time is 6 hand the reaction temperature is 85℃,the total monomer concentration is 20%.FTIR molecular structure characterization indicated that the synthesized samples were consistent with the expected structure.Gel permeation chromatography(GPC)testing the molecular weight of MA/AMPS/APEG and the M_w=3 145,a low molecular weight polymer.At a temperature of 70℃ and the addition of 100 mg/L,the inhibition efficiency of calcium carbonate was 90.12%.The inhibition performance of anti-scaling rate of results show that when the calcium concentration is high,the calcium carbonate microcrystal will enclose the polymer molecules and weaken the anti-scaling property.When the concentration is suitable,MA/AMPS/APEG scale inhibitor has good anti-scaling properties for calcium carbonate.
作者 全红平 谢林红 饶政 何帆 唐坤利 Quan Hongping;Xie Linhong;Rao Zheng;He Fan;Tang Kunli(School of Chemistry and Chemical Engineering of Southwest Petroleum University,Chengdu 610500,Sichuan,China;Oil & Gas Field Applied Chemistry Key Laboratory of Sichuan Province,Chengdu 610500,Sichuan,China;Shixi Oil field Operation Area of Xinjiang Oil field Branch Offices of China National Petroleum Corporation,Kelamayi 834000,Xinjiang,China;Zhundong Oil Production Plant of Xinjiang Oil field Branch Offices of China National Petroleum Corporation,Fukang 831511,Xinjiang,China)
出处 《精细石油化工》 CAS CSCD 北大核心 2018年第4期1-7,共7页 Speciality Petrochemicals
基金 西南石油大学科研启航项目(2015QHZ015) 油气田应用化学重点实验室开放项目(YQKF201401)
关键词 防垢剂 碳酸钙 水处理 二氧化碳饱和汽提 低相对分子质量聚合物 inhibitor calcium carbonate water treatment carbon dioxide stripping oligomeric
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