摘要
过渡金属催化的C—H键官能团化策略因其高原子和步骤经济性而备受关注.亚胺因其多样性的反应活性而在构建结构新颖的含氮化合物中得以广泛应用,侧重综述了近年来亚胺参与的C—H键官能团化/环化反应的最新研究进展,并对其反应类型和相关机理予以论述.
Transition metal-catalyzed direct C-H bond functionalization strategy has aroused wide concerns due to its high atom-economy and step-economy. Imine synthons exhibit diverse reactivities and are commonly employed to assemble nitrogen-containing complex molecules through direct C-H functionalization strategies, their reaction types and mechanisms are summarized in this paper.
作者
陈训
白丽丽
曾伟
Chen Xun;Bai Lili;Zeng Wei(School of Pharmacy,Hainan Medical University,Haikou 5 71199;School of Chemistry and Chemical Engineering,South China University of Technology,Guangzhou 510640)
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
2018年第8期1859-1871,共13页
Chinese Journal of Organic Chemistry
基金
国家自然科学基金(No.21372085)
广州市科技计划(No.156300075)
清远市科技计划(No.2014D006)资助项目~~
关键词
亚胺
过渡金属催化
C—H键官能化
氮杂环化合物
imines
transition metal-catalysis
C-H bond functionalization
azaheterocycles
