摘要
Hydrothermal assembly of Co2＋ ion, a bis-imidazole ligand BIMB（BIMB = 1,4-bis（imidazol-1-yl）benzene） and a rigid bidentate linker 2,6-naphthalenedicarboxylic acid（H2ndc）, yields a novel three-dimensional（3D） self-penetrating coordination polymer {[Co（BIMB）（ndc）]·H2O}n（1）. Complex 1 exhibits {6~5.8} topology and contains a 2D → 3D parallel polycatenated substructure. In addition, solid-state UV-vis absorption spectra of 1 were also investigated.
Hydrothermal assembly of Co2＋ ion, a bis-imidazole ligand BIMB（BIMB = 1,4-bis（imidazol-1-yl）benzene） and a rigid bidentate linker 2,6-naphthalenedicarboxylic acid（H2ndc）, yields a novel three-dimensional（3D） self-penetrating coordination polymer {[Co（BIMB）（ndc）]·H2O}n（1）. Complex 1 exhibits {6~5.8} topology and contains a 2D → 3D parallel polycatenated substructure. In addition, solid-state UV-vis absorption spectra of 1 were also investigated.
基金
Supported by the National Natural Science Foundation of China(Nos.21361023 and 21461023)
