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氧气底吹铜熔炼工艺分析及过程优化 被引量:18

Analysis and optimization of oxygen bottom blowing copper smelting process
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摘要 通过分析氧气底吹铜熔炼渣及铜锍,结合冶金过程原理,研究渣-铜锍间多组元含量的映射关系及熔炼过程优化。结果表明:铜锍中Cu、S、Fe含量之间呈现出较强的相关性;渣中Cu、SiO_2、Fe含量及渣型铁硅比m_(Fe)/m_(SiO_2)相互之间也呈现出一定的相关性;铜锍中Cu、Fe、S含量对渣中S含量的映射关系较为明显;基于铜锍中S、Cu含量和渣中S含量,或基于渣型铁硅比m_(Fe)/m_(SiO_2)和铜锍品位都可对渣中Cu含量进行预测,后者的准确度较高,说明铜锍品位和渣型对渣中Cu含量有较大影响。 Slag-matte multiphase multicomponent mapping relationship and process optimization were investigated by analyzing industrial slag and matte in oxygen bottom blowing copper bath smelting process (BBS), combined with metallurgical process principles. The results show thatw[Cu],w[S] andw[Fe] in matte have strong linear correlation.w(Cu), )(SiO2w,w(Fe) and(SiO)(Fe)2m/m in slag have certain correlation. Slag-matte multicomponent also has certain correlation, and the correlations ofw(S)?(w[Cu],w[Fe],w[S]) are obvious. Usingw[S],w[Cu] andw(S)can predictw(Cu), as well as using (SiO)(Fe)2m/m andw[Cu], but the later has higher accuracy. It shows that matte grade and slag type have deep effect on cooper in slag.
出处 《中国有色金属学报》 EI CAS CSCD 北大核心 2016年第3期689-698,共10页 The Chinese Journal of Nonferrous Metals
基金 湖南有色研究基金重点项目(YSZN2013YJ01)~~
关键词 铜冶金 氧气底吹 性能分析 过程优化 copper smelting oxygen bottom blowing performance analysis process optimization
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参考文献5

  • 1Sergei A. Degterov,Arthur D. Pelton.A thermodynamic database for copper smelting and converting[J]. Metallurgical and Materials Transactions B . 1999 (4)
  • 2R. Sridhar,J. M. Toguri,S. Simeonov.Copper losses and thermodynamic considerations in copper smelting[J]. Metallurgical and Materials Transactions B . 1997 (2)
  • 3M. Nagamori,P. Mackey.Thermodynamics of copper matte converting: Part I. Fundamentals of the noranda process[J]. Metallurgical Transactions B . 1978 (2)
  • 4Yazawa,Akira.THERMODYNAMIC CONSIDERATIONS OF COPPER SMELTING. Canadian Metallurgical Quarterly . 1974
  • 5Mackey,P.J.PHYSICAL CHEMISTRY OF COPPER SMELTING SLAGS - A REVIEW. Canadian Metallurgical Quarterly . 1982

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