摘要
通过模拟实验探讨了4种覆盖材料对洱海不同湖区沉积物溶解态总磷(DTP)、溶解态有机磷(DOP)和溶解态无机磷(SRP)释放影响及差异.结果表明:①与无覆盖对照相比,覆盖材料通过改变洱海沉积物pH和Eh及溶解性有机质(DOM)特征,降低了沉积物DTP最大释放量,其中,覆盖氧化铁对洱海北部和南部沉积物DTP释放控制效果较好,与无覆盖对照相比,释放量分别减少了44. 3%和35. 71%;而覆盖氧化铝对中部湖区沉积物DTP释放控制效果较好,与无覆盖对照相比,释放量减少了29. 6%.②覆盖铁铝氧化物对洱海不同湖区沉积物SRP和DOP释放量影响差异明显,北部湖区沉积物覆盖氧化铁后,SRP和DOP释放量分别降低了35. 6%和36. 2%,主要是因为其降低了沉积物pH和Eh,而增加了DOM活性所致;中部湖区沉积物覆盖氧化铝后,SRP和DOP释放量分别降低了28. 9%和31. 6%,与氧化铝促进了该湖区DOM活性密切相关;南部湖区沉积物覆盖氧化铁后,沉积物SRP和DOP释放量分别降低了47. 4%和16. 5%,则与覆盖氧化铁降低了该湖区沉积物pH和Eh有关.因此,如选择覆盖材料控制洱海不同湖区沉积物磷释放,北部和南部湖区应选择覆盖氧化铁,而中部湖区应选取氧化铝作为覆盖材料.
In this work, the effects of four covering materials on the release of total dissolved phosphorus (DTP), dissolved organic phosphorus (DOP), and soluble reactive P (SRP) in different sediments of Erhai Lake were simulated. The results showed that the max release of DTP was reduced in covering material, which attributed to the changes of pH, Eh and characteristics of dissolved organic matter (DOM) by the effect of covering material. The application of iron oxide material significant reduced the release of DTP in the northern and southern part of the lake, with decrease rate of 44.3% and 35.7%, respectively. by contrast, the application of aluminum oxide material significant reduced the release of DTP in the middle part sediment, with decrease rate of 29.6%. Furthermore, the release of SRP and DOP in different sediments has significant difference after added different material. In northern part of sediment, the release of SRP and DOP reduced by 35.6% and 36.2% after added iron oxide material. This is because iron oxide can reduce the pH and Eh but increase the availability of DOM in northern, and then benefits for inhibiting the release of SRP and DOP. In the middle, the release of sediment SRP and DOP reduced by 28.9% and 31.6% after added aluminum oxide material. This is because the aluminum oxide can facilitate the availability of DOM in middle, and then inhibits the release of SRP and DOP. In southern part of the lake, the release of sediment SRP and DOP reduced by 47.4% and 16.5% after added iron oxide material. This is largely attributed to the effect of iron oxide on the pH and Eh. Therefore, to control the release of P in the sediment from Lake Erhai, iron oxide material should be selected in the northern and southern parts, whereas aluminum oxide should be selected in the middle part of the lake.
作者
龚佳健
倪兆奎
肖尚斌
赵海超
席银
王圣瑞
GONG Jia-jian;NI Zhao-kui;XIAO Shang-bin;ZHAO Hai-chao;XI Yin;WANG Sheng-rui(College of Hydraulic & Environmental Engineering,Three Gorges University,Yichang 443002,China;College of Water Sciences,Beijing Normal University,Beijing 100875,China;State Key Laboratory of Environmental Criteria and Risk Assessment,Chinese Research Academy of Environmental Sciences,Beijing 100012,China;Yunnan Key Laboratory of Pollution Process and Management of Plateau Lake-Watershed, Yunnan Institute of Environmental Science,Kunming 650034,China;College of Agricultural and Forestry Science and Technology,Hebei North University,Zhangjiakou 075131 ,China)
出处
《环境科学》
EI
CAS
CSCD
北大核心
2019年第4期1826-1833,共8页
Environmental Science
基金
云南省高原湖泊流域污染过程与管理重点实验室开放基金项目(230200069)
国家万人计划项目(312232102)
关键词
沉积物
覆盖材料
溶解态有机磷
溶解态无机磷
磷释放
sediment
covering material
dissolved organic phosphorus
dissolved inorganic phosphorus
phosphate release
