期刊文献+

高耐溶剂性和稳定性的多巴胺复合纳滤膜的制备与表征 被引量:5

Dopamine Composite Nanofiltration Membrane with High Solvent Resistance and Stability
下载PDF
导出
摘要 复合纳滤膜(NF)具有多层结构,在恶劣环境中使用时容易分层,稳定性差。实验通过界面聚合法制备了复合纳滤膜,研究了该复合纳滤膜的分离性能和稳定性。将DOPA-TMC和DOPA/PIP-TMC纳滤膜在乙醇中浸泡12 d后,复合纳滤膜对刚果红的截留率仅仅下降了1.76%和1.22%(初始值99.86%、99.92%)。此外,将DOPA-TMC和DOPA/PIP-TMC纳滤膜浸泡在活性氯溶液中240 h后,仍然保持高分离性能。该纳滤膜在乙醇中具有长期的结构稳定性,在次氯酸钠溶液中具有良好的化学稳定性,在整个实验过程中未出现分层现象。 Composite nanofiltration(NF)membranes tend to delaminate and have a poor stability while applied to harsh environments due to the multi-layered structure.In this study,dopamine(DOPA)was employed to prepare NF membranes via interfacial polymerization.The separation performance and stability of NF membranes were investigated,respectively.After soaking in ethanol solvent for 12 d of both DOPA-trimesoyl chloride(TMC)NF membranes and DOPA/piperazine(PIP)-TMC NF membranes,the rejection rate of Congo red is only decreases by 1.76%and 1.22%(the original of 99.86%and 99.92%),respectively.Moreover,the separation performances of both DOPA-TMC NF and DOPA/PIP-TMC NF membranes are still excellent after soaking in the active chlorine solution for 240 h(12 g·L-1·h).The NF membranes exhibit a long-term structural stability in ethanol and a considerable chemical stability in sodium hypochlorite solution.In particular,no delamination is observed in the above experiments.
作者 高钰冰 伍丽萍 盖景刚 Yubing Gao;Liping Wu;Jinggang Gai(Polymer Research Institute of Sichuan University,State Key Laboratory of Polymer Materials Engineering,Chengdu 610065,China)
出处 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2019年第5期164-170,共7页 Polymer Materials Science & Engineering
基金 国家自然科学基金资助项目(51473097,51003067) 高分子材料工程国家重点实验室开放课题基金资助(sklpme2014-3-14)
关键词 分层 纳滤 多巴胺 界面聚合 稳定性 delamination nanofiltration dopamine interfacial polymerization stability
  • 相关文献

参考文献2

二级参考文献38

  • 1Kim, I.C., Lee, KH. and Tak, T.M., J. Membr. Sci., 2001, 183: 235.
  • 2Vander Bruggen, B., Geens, 1. and Vandecasteeke, C., Sep. Sci. Technol., 2002, 37: 783.
  • 3Bowen, W.R., Mohammad, A.W. and Hilal, N., 1. Membr. Sci., 1997, 126: 91.
  • 4Hayakawa, Y., Trasawa, N. and Hayashi, E., J. Appl. Polym. Sci., 1996,62: 951.
  • 5Lee, C., Low, K. and Gan, P., Environ. Technol., 1999,20: 99.
  • 6Philippe, C., Roberto, B. and Willy, V., J. Chern. Technol. Biotechnol., 1998,72: 289.
  • 7Zhao, Z.P., Li, J.D., Chen, J. and Chen, C.X., J. Membr. Sci, 2005, 251: 239.
  • 8Aerts, S., Vanhulsel, A., Buekenhoudt, A., Weyten, H. and Kuypers, S., J. Membr. Sci., 2006, 275: 212.
  • 9Buonomenna, M.G., Lopez, L.e., Davoli, M., Favia, P. and Agostino, R.D., Microporous and Mesoporous Mater., 2009, 120: 147.
  • 10Akbari, A., Desc1aux, S., Rouch, J.C. and Aptel, P., J. Membr. Sci., 2006, 286: 342.

共引文献37

同被引文献18

引证文献5

二级引证文献4

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部