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Controllable synthesis and tunable photocatalytic activity of TiO2 nanowires via alcohol-thermal method 被引量:5

Controllable synthesis and tunable photocatalytic activity of TiO2 nanowires via alcohol-thermal method
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摘要 Titania nanowires(TiO2-NW)with tunable aspect ratios and morphologies were directly synthesized using a simple alcohol-thermal technique.Specifically,ethanol and acetic acid were used as solvents and lithium ion was used as the capping agent to promote the conversion of titanium butoxide into TiO2-NW.The morphologies and crystal phases of TiO2-NW were determined by the molar ratio of solvents and the content(mol%)of lithium ion.The band gap of TiO2-NW with pure anatase phase is slightly bigger than that of TiO2-NW with a mixture of anatase and rutile phases.All TiO2-NW could achieve effective decolorization of methyl blue(the decolorization rate is over 95%)after 35-min ultraviolet(UV)irradiation. Titania nanowires(TiO2-NW) with tunable aspect ratios and morphologies were directly synthesized using a simple alcohol-thermal technique. Specifically,ethanol and acetic acid were used as solvents and lithium ion was used as the capping agent to promote the conversion of titanium butoxide into TiO2-NW. The morphologies and crystal phases of TiO2-NW were determined by the molar ratio of solvents and the content(mol%) of lithium ion. The band gap of TiO2-NW with pure anatase phase is slightly bigger than that of TiO2-NW with a mixture of anatase and rutile phases. All TiO2-NW could achieve effective decolorization of methyl blue(the decolorization rate is over 95%) after 35-min ultraviolet(UV) irradiation.
出处 《Rare Metals》 SCIE EI CAS CSCD 2019年第5期390-396,共7页 稀有金属(英文版)
基金 financially supported by the National Natural Science Foundation of China (No. 51408528) the Natural Science Foundation of Hebei Province, China (No. E2014203089)
关键词 NANOWIRES TIO2 PHOTOCATALYSIS Degradation PHOTOCURRENT Nanowires TiO2 Photocatalysis Degradation Photocurrent
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