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Synergistically Directed Assembly of Aromatic Stacks Based Metal-Organic Frameworks by Donor-Acceptor and Coordination Interactions 被引量:12

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摘要 A synergistically directed assembly approach to distinctive metal-organic frameworks utilizing both donor-acceptor (D-A) interaction from aromatic systems and coordination interactions is presented.Based on such an approach,the coronene-tpt (tpt =2,4,6-tri(4-pyridyl)-1,3,5-triazine) stacks based coronene-MOF-1-4 have been successfully fabricated.Their structural discrepancies with coroneneabsent control products,1'-4',illustrate clearly the significance of coronene-tpt based D-A interactions in these architectures.All these coronene-MOFs contain varied coronene-tpt stacks as organic secondary building blocks (SBUs),which are closely interrelated with the coordination based framework structures.Moreover,porous coronene-MOF-1 and-2 exhibit high physicochemical stability and significant light hydrocarbons storage and separation performances.
出处 《Chinese Journal of Chemistry》 SCIE CAS CSCD 2019年第9期871-877,I0002,共8页 中国化学(英文版)
基金 This work was supported by the National Natural Science Foundation of China (Nos. 21421001, 21531005, 91856124, and 21875115) the Programme of Introducing Talents of Discipline to Universities (B18030) the General Financial Grant from the China Postdoctoral Science Foundation (No. 2017M621056).
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