期刊文献+

硝酸钐/硝酸镝/硝酸铒与组氨酸液-液反应的热动力学 被引量:2

The Thermokinetics of the Liquid-Li quid Reaction of Samarium Nitrate /Dysprosium Nitrate /Erbiu m Nitrate with Histidine
下载PDF
导出
摘要 The thermokinetics of liquid-liqui d reaction of samarium nitrate /dysp rosium nitrate /erbium nitrate with histidine are studied using a microcalorimeter.On the basis of experime ntal and calculated results,three t hermo-dynamic parameters(the activation enthalpy,the active entropy and the activation free energy),the rate constant,three kinetic parameters(the activation energy,the pre-exponential constant and the reaction order)are obtained.The influence of temperature on the t itled reaction and the synthetic con dition of the complex have been discu ssed. The thermokinetics of liquid-liqui d reaction of samarium nitrate /dysp rosium nitrate /erbium nitrate with histidine are studied using a microcalorimeter.On the basis of experime ntal and calculated results,three t hermo-dynamic parameters(the activation enthalpy,the active entropy and the activation free energy),the rate constant,three kinetic parameters(the activation energy,the pre-exponential constant and the reaction order)are obtained.The influence of temperature on the t itled reaction and the synthetic con dition of the complex have been discu ssed.
出处 《无机化学学报》 SCIE CAS CSCD 北大核心 2002年第12期1237-1240,共4页 Chinese Journal of Inorganic Chemistry
基金 国家自然科学基金资助项目(No.29871023 20171036) 稀土材料化学及应用国家重点实验室资助项目。
关键词 硝酸钐 硝酸镝 硝酸铒 液-液反应 组氨酸 稀土硝酸盐 微热量法 热动力学 稀土氨基酸配合物 histidine rare earth nitr ate microcalorimeter thermokinetics
  • 相关文献

参考文献1

  • 1MarssL.R. Chemical Reviews . 1976

同被引文献71

引证文献2

二级引证文献7

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部