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功能化纳米SiO2改性环氧树脂复合材料及其摩擦磨损行为与机制 被引量:12

Tribological behavior and wear mechanism of modified nano-SiO2 reinforced epoxy composites
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摘要 运用共价官能化技术,实现纳米SiO2表面接枝3-氨丙基三乙氧基硅烷(APTES)改性(T-SiO2),并制备功能化纳米SiO2改性环氧树脂复合材料(T-SiO2/EP),分析改性后纳米SiO2表面官能团和化学元素的变化规律,测试T-SiO2/EP的主要力学性能,研究其在干摩擦条件下的摩擦磨损行为与机制。结果表明:功能化纳米SiO2的引入,有效改善了环氧树脂的力学与摩擦学性能,且当功能化纳米SiO2含量为2%时(质量分数,下同),环氧复合材料(2%T-SiO2/EP)的显微硬度和断裂韧度均达到最大值(70.2HD和1.02MPa·m^1/2),并具有优异的减摩耐磨性能。干摩擦条件下,2%T-SiO2/EP复合材料的摩擦因数和磨损失重分别为0.49和1.7mg,较纯环氧树脂分别降低了31.9%和34.6%,较未改性纳米SiO2增强的环氧树脂复合材料(U-SiO2/EP)分别降低了14%和10.5%,并对相应的磨损机理进行了分析。 Nano-SiO2 surface grafted APTES(T-SiO2)was realized by covalent functionalization technology,and functionalized nano-SiO2 modified epoxy resin composite(T-SiO2/EP)was prepared.The surface functional groups and chemical elements of the functionalized nano-SiO2were analyzed and the mechanical and tribological properties of the T-SiO2/EP were tested.The results show that the mechanical and tribological properties of the epoxy resin are effectively improved due to the introduction of functionalized nano-SiO2.When the content of functionalized nano-SiO2 is 2%(mass fraction,same as below),the microhardness and fracture toughness of the composites(2%T-SiO2/EP)can reach the maximum,which are 70.2 HD and 1.02 MPa·m^1/2 respectively,moreover,in dry friction condition,the friction coefficient and the wear loss reach the minimum,which are 0.49 mg and 1.7 mg respectively.Compared with pure epoxy resin,they are reduced by 31.9%and 34.6%,and compared with 2%unmodified nano-SiO2 reinforced epoxy resin composite,they are reduced by 14%and 10.5%,and the corresponding wear mechanism is analyzed.
作者 田晋 高立 蔡滨 齐泽昊 谭业发 TIAN Jin;GAO Li;CAI Bin;QI Ze-hao;TAN Ye-fa(Institute of Field Engineering,Army Engineering University of PLA,Nanjing 210007,China;Army Nanjing Military Agency,Nanjing 210024,China)
出处 《材料工程》 EI CAS CSCD 北大核心 2019年第11期92-99,共8页 Journal of Materials Engineering
关键词 环氧树脂(EP) 纳米SIO2 复合材料 表面改性 摩擦磨损 epoxy resin nano-SiO2 composites surface modification friction and wear
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  • 1雷毅,彭旭东,张雁翔,郭建良.基于超高分子量聚乙烯及其复合材料摩擦学研究进展[J].化工进展,2004,23(7):727-730. 被引量:14
  • 2RP谢尔登.聚合物基复合材料[M].北京:机械工业出版社,1989..
  • 3陈平,刘胜平著.环氧树脂[M].北京:化学工业出版社,1997
  • 4巴拉姆鲍伊姆HK.高分子化合物力化学[M].江畹兰,译.北京:化学工业出版社,1982,73:162—169.
  • 5Xiong Dangsheng,Ge Shirong.Eriction and wear properties of UHMWPE/Al2O3 ceramic under different lubricating conditions[J].Wear,2001(250):242-245.
  • 6Handbook Committee.ASM Handbook[M].ASM International,Materials Park,USA,1992,18.
  • 7谢尔登 R.P.聚合物基复合材料[M].北京:机械工业出版社,1989.
  • 8Shi G,Zhang M Q,Rong M Z,et al.Friction and wear of low nanometer Si3N4 filled epoxy composites[J].Wear,2003,254:784-796.
  • 9Ji Q L,Zhang M Q,Rong M Z,et al.Friction and wear of epoxy composites containing surface modified SiC nanoparticles[J].Tribology Letters,2005,20:115-123.
  • 10Wetzel B,Haupert F,Zhang M Q.Epoxy nanocomposites with high mechanical and tribological performance[J].Composites Science and Technology,2003,63:2 055-2 067.

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