摘要
设计了表面活性剂辅助乳化微萃取(SAEME)-高效液相色谱法测定饮水中酞酸酯实验项目。该项目以分散液液微萃取技术为基础,表面活性剂代替该技术中的分散剂,对比了阳离子表面活性剂CTAB、阴离子表面活性剂SDS和非离子型表面活性剂Triton X-100的分散效果。实验结果表明,该设计取得了较好的萃取效果,同时减少了有机溶剂的使用量,高效低耗,环境友好。
An innovative experiment entitled "determination of phthalate esters in drinking water by surfactant assisted emulsification microextraction( SAEME) combined with high performance liquid chromatography " was designed by using surfactant assisted extraction technique. The design was based on the new procedure,dispersive liquid-liquid microextraction( DLLME),but the dispersant was replaced by surfactant. The dispersion effect of the cationic surfactant CTAB,the anionic surfactant SDS and the non-ionic surfactant Triton X-100 was compared,the concentration and volume of the surfactant were determined by referencing the critical micelle concentration( CMC), and the understanding of the relationship between the state of the substance and the chemical environment,the salting-out effect was also deepened. By comparing the experimental results,the better extraction effect was obtained. At the same time,the amount of organic solvent was reduced. The advantages of this method are high efficiency and low consumption,environment friendly and beneficial to the operators.
作者
曹江平
马贵
赵文霞
刘丽娜
徐地红
易宗慧
CAO Jiangping;MA Gui;ZHAO Wenxia;LIU Lina;XU Dihong;YI Zonghui(College of Chemistry and Chemical Engineering,Ningxia Normal University,Guyuan 756000,Ningxia,China;Engineering and Technology Research Center of Liupanshan Resources,Ningxia Normal University,Guyuan 756000,Ningxia,China)
出处
《实验室研究与探索》
CAS
北大核心
2019年第10期187-189,共3页
Research and Exploration In Laboratory
基金
国家自然科学基金项目(21561027)
宁夏科技创新领军人才项目(KJT2016004)
宁夏高等学校一流学科建设资助项目(NXYLXK2017B11)
宁夏重点研发计划(科技支撑)项目(2018YBZD1466)
宁夏师范学院六盘山资源工程技术研究中心资助项目(HG18-01)
宁夏师范学院校级科研项目(NXSFZDA1812)
关键词
实验设计
表面活性剂辅助乳化微萃取
酞酸酯
design of experiment
surfactant assisted emulsification microextraction
phthalate esters
