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Photo-induced phosphorus radical involved semipinacol rearrangement reaction:Highly synthesis ofγ-oxo-phosphonates

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摘要 Hydroxyphosphoric acids display the unique biological activities,and they have some attractive prospects as clinical drug moleculars.Herein,a new approach for the synthesis ofγ-oxo-phosphonates(the precursor of hydroxyphosphoric acid)has been established through the semipinacol rearrangement tactic involved the photo-induced phosphorus radical process.Most important,this transformation is avoid of the external oxidants,and occurs very well under the sunlight irradiation,meanwhile theγ-oxo-phosphonate was easily derivatized to obtainγ-hydroxyphosphoric acid,thus highlights the synthesis value of this method.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2020年第3期677-680,共4页 中国化学快报(英文版)
基金 the National Natural Science Foundation of China(No.21532001) International Joint Research Centre for Green Catalysis and Synthesis,Gansu provincial Sci.&Tech.Department(No.2016B01017)for financial support。
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