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Macroporous 3D carbon-nitrogen(CN)confined MoO_(x) catalyst for enhanced oxidative desulfurization of dibenzothiophene 被引量:3

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摘要 Macroporous 3D carbon doped with nitrogen confined Mo catalyst(MoO_(x)@CN)had been prepared by a facile one-step pyrolysis technique using silica as a template and was employed for oxidative desulfurization(ODS)of dibenzothiophene(DBT)in model fuel with H2O_(2) as oxidant.The effect of different ope rating conditions(i.e.,reaction te mperature and time,catalyst dosage,H2O_(2)/DBT(O/S)molar ratio)were also systematic investigated.Under the optimal reaction condition,MoO_(x)@CN catalyst exhibited highly excellent ODS performance toward DBT,the highest sulfur removal efficiency can be up to 99.9%and sulfur content was wiped out from 800 ppm to 10 ppm.Due to the robust 3D structure promoting rapid transfer,in addition to the increased number of active sites induced by the Mo vacancies,the catalyst,prepared using chitosan and ammonium heptamolybdate in a mass ratio of 1:0.5,displayed rapid kinetics and low activation energy in the oxidation of dibenzothiophene.Moreover,it exhibited excellent recyclability after five cycles without any obvious decrease in catalytic activity for the oxidative desulfurization reaction.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2020年第10期2819-2824,共6页 中国化学快报(英文版)
基金 the Applied Basic Research Project of Science and Technology Department of Sichuan Province(No.2020YJ0418)。
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