摘要
Recently,to ameliorate the forthcoming energy crisis,sustainable energy conversion and storage devices have been extensively investigated.Potassium-ion batteries(KIBs)have aroused widespread attention in these very active research applications due to their earth abundance and similar low redox potential compared to Li-ion batteries(LIBs).It is critical to develop electrode materials with large ion diffusion channels and robust structures for long cycling performance in KIBs.Metal coordination materials,including metal-organic frameworks,Prussian blue,and Prussian blue analogue,as well as their composites and derivatives,are known as promising materials for high-performance KIBs due to their open frameworks,large interstitial voids,functionality and tailorability.In this review,we give an overview of the recent advances on the application of metal coordination materials in KIBs.In addition,the methods to enhance their K-ion storage properties are summarized and discussed,such as morphology engineering,doping,as well as compositing with other materials.Ultimately,some prospects for future research of metal coordination materials for KIBs are also proposed.
基金
the Program for Changjiang Scholars and Innovative Research Team in University(No.IRT16R21)
the Chinese 02 Special Fund(No.2017ZX02408003)
the Scientific and Technological Project of Henan Province(No.182102210297)
the Open Fund of National Joint Engineering Research Center(Nos.HKDNM201807 and HKDNM2019017)
the Science Foundation for Youths of Henan University of Science and Technology(No.2013QN006)
the Student Research Training Plan of Henan University of Science and Technology(No.2020026)
the National Undergraduate Innovation and Entrepreneurship Training Program(No.202010464031)。
