摘要
The hierarchical hollow structures of electrode materials s of supercapacitors is effective for the large specific surface area and fast ions and charge transports.Cu nanowires as self-engaged templates provide sites and paths for the nucleation and growth of the ZIF-67.Meanwhile,Cu atoms can disperse into metal organic frameworks(MOFs)to form Cu-Co mixed oxides and construct heterostructures.In this case,Cu nanowires are used as a template and an activated part to improve the internal electronic structures.The electrochemical performance can be improved due to these features.Herein,Cu nanowires and MOFs are combined via a mild and efficient approach to fabricate Cu-Co-O/CuO electrode materials.This electrode exhibits excellent electrochemical performance with a specific capacitance of 834.1 F g^(-1) at 1 A g^(-1).The assembled asymmetric supercapacitor(ASC)shows an ultra-high energy density of 40.7 W h kg^(-1) at a power density of 915 W kg^(-1) and a good capacitance retention after 8000 cycles in a 2 M KOH aqueous solution.The results otained in this work indicate a strategy of the combination of reactive metals with metal organic frameworks used as electrode materials for electrochemical supercapacitors.
基金
supported by the National Natural Science Funds[grant number 51821091,51872233]
the Natural Science Foundation of Shaanxi Province[grant number 2018JM5044]。
