摘要
为提高聚酰胺6(PA6)纤维的阻燃性能,以10-(2,5-二羧基苯氧基)-10-氢-9-氧杂-10-磷杂菲-10-氧化物(DOPODP)为共聚阻燃剂,复配二硫化钼(MoS2)或硫化锌(ZnS),制备DOPODP共聚协效阻燃PA6,经熔融纺丝制备阻燃PA6纤维,并对其结构、性能及阻燃机制进行研究。结果表明:DOPODP经共聚法成功引入PA6,DOPODP可提高PA6的阻燃性能,但其熔融温度、结晶温度等下降;引入协效阻燃剂后,阻燃PA6垂直燃烧(UL94)级别为V-0级,极限氧指数(LOI值)达30%以上;DOPODP对PA6主要表现为气相阻燃作用,DOPODP分解产生含磷自由基可捕获活性自由基,协效阻燃剂可促进PA6成炭;相比PA6纤维,阻燃PA6纤维力学性能下降,而织物的LOI值提高。
In order to improve the flame retardancy of polyamide 6(PA6)fibers,a flame retardant was synthesized by copolymerization with 10-(2,5-dicarboxyl phenoxyl)-9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide(DOPODP)and combination of molybdenum disulfide(MoS2)or zinc sulfide(ZnS),the flame retardant PA6 fibers were prepared via melt spinning.The structure,properties,and the flame-retardant mechanism of the co-PA6 and its fibers were also studied.The results show that the DOPODP had been introduced into PA6 molecular chains,the flame retardancy of the copolymer was improved,but the melting temperature and crystallization temperature were reduced.The synergistic flame retardant PA6 achieved a V-0 rating according to the UL94 criterion with an LOI value greater than 30%.The study of the flame-retardant mechanism indicated that the DOPODP in PA6 mainly take effects in gas phase,DOPODP could decompose to phosphorus radicals.In addition,with the introduction of synergistic flame retardants,the char content of flame retardant PA6 was increased.Compared with PA6 fiber,the mechanical properties of flame retardant PA6 fibers were decreased,and the LOI value of the fabrics increased.
作者
刘可
陈爽
肖茹
LIU Ke;CHEN Shuang;XIAO Ru(Key Laboratory of High-Performance Fibers & Products, Ministry of Education, Donghua University, Shanghai 201620, China)
出处
《纺织学报》
EI
CAS
CSCD
北大核心
2021年第7期11-18,共8页
Journal of Textile Research
基金
国家重点研发计划项目(2017YFB0309000)
中央高校基本科研业务费专项资金资助项目(2232021G-02)。
关键词
聚酰胺6
阻燃剂
二硫化钼
硫化锌
共聚法
阻燃纤维
功能性纤维
polyamide 6
flame retardant agent
molybdenum disulfide
zinc sulfide
copolymerization
flame retardant fiber
functional fiber
