摘要
本文用气相色谱研究了O-烷基硫代磷酰二氯的重排反应。提出了重排反应的机理,并运用软硬酸碱理论进行了讨论。第一次用重排转位的方法制得了S-异丙基硫代磷酰二氯。
The results of using gas chromatography to follow the reactions revealed that four different reactions were existed simultaneously in the isomerization of O-alkyl phosphorodichloridothioates. They were considered as a combination of rearrangement, decomposition and disproportion reaction as well as hydrolysis. The reaction mechanism was preliminarily discussed according to HSAB theory. It was the first time that S-isopropyl phosphorodichloridothioate was synthesized by using the isomerization method.
作者
张景龄
胡水生
Zhang Jingling;Hu Shuisheng(Department of Chemistry,Central China Normal University,Wuhan)
出处
《高等学校化学学报》
SCIE
EI
CAS
1983年第3期329-334,共6页
Chemical Journal of Chinese Universities
