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Crystal growth,spectral properties and Judd-Ofelt analysis of Pr:CaF_(2)-YF_(3)

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摘要 The 0.6 at.%Pr^(3+)-doped CaF_(2)-YF_(3)crystal was successfully grown by the temperature gradient technique(TGT).X-ray diffraction analysis showed that the grown crystal still had cubic structure.The absorption spectrum,emission spectrum,Judd-Ofelt analysis and fluorescence decay curve at room temperature were discussed.The fluorescence lifetime of Pr:CaF_(2)-YF_(3)crystal was 45.46µs,and theσem·τof ^(3)P0→^(3)H_(6) and ^(3)P0→^(3)F_(2) transitions were calculated to be 80.92×10^(−20) cm^(2)·µs and 388.7×10^(−20) cm^(2)·µs,respectively.The FWHMs are 20.1 nm and 6.8 nm,which are higher than those of Pr:LiYF_(4),Pr:LiLuF_(4),Pr:LiGdF_(4) and Pr:BaY_(2)F_(8) crystals.The results show that the Pr:CaF_(2)-YF_(3)crystal is expected to achieve 605 nm orange light and 642 nm red light laser operation.
作者 田杰 曹笑 王无敌 刘坚 董建树 胡冬华 王庆国 薛艳艳 徐晓东 徐军 Jie Tian;Xiao Cao;Wudi Wang;Jian Liu;Jianshu Dong;Donghua Hu;Qingguo Wang;Yanyan Xue;Xiaodong Xu;Jun Xu(School of Physics Science and Engineering,Institute for Advanced Study,Tongji University,Shanghai 200092,China;Jiangsu Key Laboratory of Advanced Laser Materials and Devices,School of Physics and Electronic Engineering,Jiangsu Normal University,Xuzhou 221116,China)
出处 《Chinese Physics B》 SCIE EI CAS CSCD 2021年第10期624-629,共6页 中国物理B(英文版)
基金 supported by the National Natural Science Foundation of China(Grant Nos.61805177,61861136007,and 61621001).
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