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Fluorine-containing agrochemicals in the last decade and approaches for fluorine incorporation 被引量:2

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摘要 In this review, the methodologies for fluorine incorporation of 40 fluorine-containing agrochemicals that received an international standardization organization(ISO) name during the last decade are described.The predominant approach for fluorine introduction of these agrochemicals is to use a fluorine-containing building block. Here we present how the fluorine-containing building blocks are introduced into these agrochemicals. The synthetic methods of fluorine-containing building blocks that are not easily available are also specifically discussed. Fluoroarenes, difluomethylarenes and trifluomethylarenes are the main building blocks that have been used in this review. Fluorine-containing small molecules, such as alcohol,amine, ketoester, olefin are also widely used. The only example of late-stage fluorination is the synthesis of fungicide quinofumelin. We believe the fluorine introduction methods described here can provide ideas for the development of new and economical pesticide synthetic routes, and stimulate researchers to develop new fluorine incorporation methods and create new pesticides.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2022年第2期626-642,共17页 中国化学快报(英文版)
基金 National Natural Science Foundation of China (Nos.21732002,22077071) Frontiers Science Center for New Organic Matter,Nankai University (No.63181206) for generous financial support for our programs。
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