摘要
综述了通过催化的方式将硝基芳烃转化为氨基芳烃的研究。传统的催化技术以铁粉作为催化剂,易造成大量固体废渣和水体污染物,这也成为研究改进的重点。介绍了常温热催化和光催化还原硝基芳烃反应的研究现状和优劣势,着重介绍了催化剂的种类和特点,在此基础上讨论了传统热催化和光催化的催化机理。对催化还原硝基芳烃反应的现状和局限进行了论述。对调控反应路径的可能性及反应的未来发展进行了展望。
This paper reviews the research on the catalytic conversion of nitroaromatics to aminoaromatics.Traditional catalytic technology uses iron powder as a catalyst,which causes a large amount of solid waste and water pollutants,has become the focus of research.Herein,research status and advantages or disadvantages of room temperature thermal catalysis and photocatalytic reduction of nitroaromatics are mainly introduced,and the types and characteristics of catalysts are highlights.Also,the catalytic mechanisms of traditional thermal catalysis and photocatalysis are discussed,and the limitations of the catalytic reduction of nitroaromatics.The possibility of regulation of reaction path and the future development of the reaction are prospected.
作者
黄易旋
卓康基
徐娟
张燕辉
HUANG Yi-xuan;ZHUO Kang-ji;XU Juan;ZHANG Yan-hui(College of Chemistry,Chemical Engineering and Environment,Minnan Normal University,Zhangzhou 363000,China)
出处
《应用化工》
CAS
CSCD
北大核心
2022年第6期1793-1798,共6页
Applied Chemical Industry
基金
国家自然科学基金青年项目(21703094,21703180)
福建省自然科学基金面上项目(2019J01743)
漳州市自然科学基金(ZZ2020J02)。
关键词
还原硝基芳烃
催化剂
反应机理
光催化
室温热催化
reduction of nitroaromatics
catalyst
reaction mechanism
photocatalysis
thermocatalytic
