期刊文献+

Au/Ag双金属纳米团簇的功能化及其传感应用

Functionalization and sensing application of Au/Ag bimetallic nanoclusters
下载PDF
导出
摘要 金属纳米团簇(NCs,尺寸通常小于2 nm)是一类新型的发光纳米材料,由于具有稳定性高、生物相容性好、毒性低等优点成为分析传感领域研究热点。Au/Ag双金属纳米团簇由于“银效应”使其比传统的AuNCs和AuNCs具有更高的量子产率和更强的稳定性,具有更广阔的应用前景。该文综述近年来Au/Ag双金属纳米团簇的表面功能化及其在分析传感方面的研究进展和分析原理,具体内容包括肽链、蛋白质、DNA对Au/Ag纳米团簇的表面功能化以及功能化的纳米团簇对金属离子、生物小分子和生物酶的分析检测应用。最后总结当前Au/Ag纳米团簇的合成及其在传感分析方面面临的挑战,并对今后的发展进行展望。希望能为Au/Ag纳米团簇在生物传感领域进一步发展提供参考。 Metal nanoclusters( NCs, usually smaller than 2 nm in size), as a new type of luminescent nanomaterials, have become a research hotspot in the field of analytical sensing due to Due to their high stability, good biocompatibility, and low toxicity. Au/Ag bimetallic nanoclusters have higher quantum yield and stronger stability than traditional AuNCs and AuNCs due to the “silver effect ”, and have a broader application prospect. In this paper, the surface functionalization of Au/Ag bimetallic nanoclusters in recent years and its research progress and analysis principle in analytical sensing are reviewed. This paper specifically introduced the functionalization of peptide chains, proteins, and DNA for nanoclusters, and its application in the analysis of metal ions, biological small molecules, and biological enzymes. Finally, the current synthesis of Au/Ag nanoclusters and their challenges in sensing detection are summarized, and an expectation for the future development has been made. It is hoped to provide reference for the further development of Au/Ag nanoclusters in the field of biosensing.
作者 邓文清 王滨 王忠 张苏敏 潘义 黄科 DENG Wenqing;WANG Bin;WANG Zhong;ZHANG Sumin;PAN Yi;HUANG Ke(National Institute of Measurement and Testing Technology,Chengdu 610056,China;College of Chemistry and Materials Science,Sichuan Normal University,Chengdu 610066,China)
出处 《中国测试》 CAS 北大核心 2022年第9期53-62,共10页 China Measurement & Test
基金 国家标准物质资源共享平台资助项目(APT2002-1)。
关键词 Au/Ag纳米团簇 功能化 分析传感 金属离子 生物分子 Au/Ag NCs functional analytical sensing metal ion biomolecules
  • 相关文献

参考文献9

二级参考文献104

  • 1黄鹏宇,李奕君,张天牧,何苗,汪恂.水中磺胺对甲氧嘧啶抗生素的平面波导免疫传感器检测[J].环境化学,2020,39(2):433-440. 被引量:5
  • 2夏云生,曹春,朱昌青.Selective Detection of Mercury(Ⅱ) and Copper(Ⅱ) Based on the Opposite Size-dependent Fluorescence Quenching of CdTe Quantum Dots[J].Chinese Journal of Chemistry,2007,25(12):1836-1841. 被引量:4
  • 3Jin, R. C. Quantum sized, thiolate-protected gold nanoclusters. Nanoscale 2010, 2, 343-362.
  • 4Laaksonen, T.; Ruiz, V.; Liljeroth, P.; Quinn, B. M. Quantised charging of monolayer-protected nanoparticles. Chem. Soc. Rev. 2008, 37, 1836-1846.
  • 5Li, G.; Jin, R. C. Atomically precise gold nanoclusters as new model catalysts. Acc. Chem. Res. 2013, 46, 1749-1758.
  • 6Zheng, J.; Zhou, C.; Yu, M. X.; Liu, J. B. Different sized luminescent gold nanoparticles. Nanoscale 2012, 4, 4073- 4083.
  • 7Negishi, Y.; Nobusada, K.; Tsukuda, T. Glutathione-protected gold clusters revisited: Bridging the gap between gold(I)- thiolate complexes and thiolate-protected gold nanocrystals. J. Am. Chem. Soc. 2005, 127, 5261-5270.
  • 8Negishi, Y.; Takasugi, Y.; Sato, S.; Yao, H.; Kimura, K.; Tsukuda, T. Kinetic stabilization of growing gold clusters by passivation with thiolates. ,1. Phys. Chem. B 2006, 110, 12218-12221.
  • 9Kumar, S.; Bolan, M. D.; Bigioni, T. P. Glutathione-stabilized magic-number silver cluster compounds. Jr. Am. Chem. Soc. 2010, 132, 13141-13143.
  • 10Yu, Y.; Chen, X.; Yao, Q. F.; Yu, Y.; Yan, N.; Xie, J. P. Scalable and precise synthesis of thiolated Aul0-t2, Auls, Aul8, and Au25 nanoclusters via pH controlled CO reduction. Chem. Mater. 2013, 25, 946-952.

共引文献33

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部