摘要
基于刚性、多孔性和多功能性,以及模块化优化、合理的设计和集成、可调谐和光化学性能等优点,卟啉网状结构材料已被证明是金属单原子锚定的优良载体,并在CO_(2)光催化还原领域拓展了一种新的载体.我们主要总结了近5年来以反应卟啉网状结构材料为载体的单原子催化剂光催化CO_(2)还原反应的最新研究进展,提出并探讨了该多相催化剂光催化CO_(2)还原的应用前景以及面临的挑战.
Based on the rigidity,porosity and versatility,as well as modular optimization,reasonable design and integration,tunability and photochemical properties of porphyrin network structure materials,which is an excellent support material for metal single atom anchoring,and expands a new way for photocatalytic CO_(2) reduction.In this paper,the latest five years progress in photocatalytic reduction of CO_(2) by single-atom catalysts with porphyrin reticular materials is summarized,and the application prospect and challenges of this heterogeneous catalysis are proposed and discussed.
作者
左国防
杨本群
王鹏
廖天录
ZUO Guo-fang;YANG Ben-qun;WANG Peng;LIAO Tian-lu(Key Laboratary for New Molecule Material Design and Function of Gansu Province,Tianshui 741000,China;College of Chemical Engineering and Technology,Tianshui Normal University,Tianshui 741000,China)
出处
《分子催化》
CAS
CSCD
北大核心
2023年第3期305-315,I0004,共12页
Journal of Molecular Catalysis(China)
基金
国家自然科学基金项目(项目编号:21465021)
中国科学院“西部之光”-“西部青年学者”项目(2020)。