摘要
透明陶瓷是一种具有广阔应用前景的无机非金属材料,但以粉末烧结为主的传统制备策略存在依赖高质量原料粉体、需要长时间高温处理、设备和工艺复杂、生产成本高等技术限制。玻璃晶化法是通过调控晶化过程实现玻璃全部结晶并且获得透明陶瓷的新方法,因其可以克服与传统透明陶瓷加工相关的技术困难,并在合成高致密度、无气孔、非立方相、纳米结构透明陶瓷等方面具有独特的优势,而受到人们的广泛关注。本文首先从玻璃晶化法制备氧化物透明陶瓷的工艺方法和组分体系两方面入手,详细概述了该方法的发展历程和研究现状。接着,指出了目前研究中存在的问题,并对其未来发展前景进行了展望,以期该方法能够广泛应用于制备下一代高性能透明陶瓷材料。
Transparent ceramic is a kind of inorganic nonmetallic material with broad application prospects.However,the traditional preparation strategy based on powder sintering has technical limitations of relying on high-quality raw material powder,requiring long time high temperature treatment,complex equipment and process,and high production cost.Glass crystallization is a new method to achieve full crystallization of glass and obtain transparent ceramics by controlling the crystallization process.This method can overcome the technical difficulties associated with the traditional transparent ceramic processing.Meanwhile,it also shows unique advantages in preparing high density,pore-free,non-cubic phase,nanostructured transparent ceramics and has attracted significant attention.In this paper,the development and research status of glass crystallization method were reviewed in detail from two aspects:fully glass-crystallization of oxide transparent ceramics and related component systems.Then,the problems existing in the current research were pointed out,and the future development prospects were prospected.It is expected that this method can be widely used to prepare the next generation of high performance transparent ceramic materials.
作者
周春鸣
陈航
陈旭
李建强
曹月
李延彬
周天元
邵岑
陈士卫
康健
陈浩
张乐
ZHOU Chunming;CHEN Hang;CHEN Xu;LI Jianqiang;CAO Yue;LI Yanbin;ZHOU Tianyuan;SHAO Cen;CHEN Shiwei;KANG Jian;CHEN Hao;ZHANG Le(School of Physics and Electronic Engineering,Jiangsu Normal University,Xuzhou 221116,China;School of Materials Science and Engineering,University of Science and Technology Beijing,Beijing 100083,China;School of Physics and New Energy,Xuzhou Institute of Technology,Xuzhou 221000,China;Jiangsu Xiyi Adv.Mater.Research Institute of Industrial Technology,Xuzhou 221400,China;Xuzhou Conner Ceramic Technology Co.Ltd.,Xuzhou 221400,China)
出处
《人工晶体学报》
CAS
北大核心
2023年第9期1555-1569,共15页
Journal of Synthetic Crystals
基金
国家重点研发计划(2021YFB3501700)
国家自然科学基金(52302141,52202135,61975070,51902143,61971207)
江苏省高校优势学科建设项目(PAPD)
江苏省重点研发项目(BE2019033,BE2021040)
江苏省自然科学基金(BK20191467,BK20221226)
江苏省国际科技合作项目(BZ2019063,BZ2020045,BZ2020030)
江苏省高等学校自然科学基金(22KJB140011,19KJB430018,20KJA430003)
徐州市技术创新专项(KC19250,KC20201,KC20244,KC21379)
先进材料与电子元器件国家重点实验室开放课题(FHR-JS-202011017)
江苏省研究生科研与实践创新计划(KYCX21_2568)。
关键词
玻璃晶化法
玻璃
氧化物透明陶瓷
非立方相
纳米结构
组分体系
glass crystallization method
glass
oxide transparent ceramics
non-cubic phase
nanostructure
component system
