摘要
强氢键是介于氢键和共价键之间的一种相互作用。自1968年发现[HX2]^(-)和[HXY]^(-)结构具有强氢键特征以来,关于“短、强”或“低势垒”氢键的研究一直成了人们感兴趣的话题。着重介绍了强氢键的电子结构以及其在生物、化学和材料设计等方面的应用,最后对强氢键未来在分子设计领域的发展进行了展望。
A“strong hydrogen bond”is a kind of interaction that possesses the strength between hydrogen bond and covalent bond.The study of"short,strong"or"low barrier"hydrogen bonds has been a topic of interest since the structures of[HX2]^(-)and[HXY]^(-)were found to feature strong hydrogen bonding characteristics in 1968.In this paper,the electronic structure of strong hydrogen bond and its applications in biology,chemistry and material design were reviewed.In the end of the article,the future development of strong hydrogen bond in molecular design was prospected.
作者
王晓娟
丁益宏
田晓
WANG Xiaojuan;DING Yihong;TIAN Xiao(College of Chemistry and Materials Engineering,Wenzhou University,Wenzhou Zhejiang 325035,China;School of Mathematics and Physics,Hebei GEO University,Shijiazhuang Hebei 050031,China)
出处
《辽宁化工》
CAS
2024年第2期250-253,共4页
Liaoning Chemical Industry
基金
国家自然科学基金(项目编号:22073069、21773082)
河北地质大学2023年度国家预研项目(项目编号:QN2022006)。
关键词
强氢键
电子结构
材料设计
Strong hydrogen bond
Electronic structure
Material design
