摘要
以石墨相氮化碳(g-C_(3)N_(4))和二水合钨酸钠为原料,采用水热合成法制备了复合材料g-C_(3)N_(4)/WO_(3)•H_(2)O(CNW-1),通过XRD、XPS、SEM、TEM对其进行了表征,探究了298 K、0.1 MPa条件下其对CO_(2)的可见光催化还原性能,并提出了可能的反应机理。通过调控WO_(3)结晶水含量可以实现CO和CH4的产率调节,在反应10 h后,CNW-1具有最高的CH4产率(0.33μmol/g),而g-C_(3)N_(4)/WO_(3)(CNW)具有最高的CO产率(0.67μmol/g)。该研究为CO_(2)选择性还原为C1化合物提供了一种有效策略,同时突出了以g-C_(3)N_(4)作为半导体构建Z型光催化体系在催化领域的应用潜力。
Composite material g-C_(3)N_(4)/WO_(3)•H_(2)O(CNW-1)was synthesized by hydrothermal reaction from graphite phase carbon nitride(g-C_(3)N_(4))and sodium tungstate dihydrate.The composite material obtained was then characterized by XRD,XPS,SEM and TEM,and its visible light catalytic CO_(2) reduction performance at 298 K and 0.1 MPa was evaluated,the possible reaction mechanism was proposed.It was found that the yield of CO and CH4 could be regulated by adjusting the crystal water content in tungsten trioxide.CNW-1 had the highest yield of CH4(0.33μmol/g),while g-C_(3)N_(4)/WO_(3)(CNW)had the highest CO yield(0.67μmol/g)after 10 h of reaction.This study provides an effective strategy for the selective reduction of CO_(2) to C1 compounds,and highlights the potential application of Z-scheme photocatalytic systems constructed from g-C_(3)N_(4) semiconductor in the field of catalysis.
作者
张健
翁森
石俊杰
蔡静宇
肖龙强
ZHANG Jian;WENG Sen;SHI Junjie;CAI Jingyu;XIAO Longqiang(College of Chemical Engineering,Fuzhou University,Fuzhou 350108,Fujian,China;Qingyuan Innovation Laboratory,Quanzhou 362801,Fujian,China)
出处
《精细化工》
EI
CAS
CSCD
北大核心
2024年第4期858-864,871,共8页
Fine Chemicals
基金
福建省自然科学基金项目(2022J05128)
福建省中青年教师教育科研项目(JAT200003)
清源创新实验室重点项目(00221003)。
关键词
二氧化碳
光催化还原
石墨相氮化碳
三氧化钨
Z型光催化剂
催化技术
carbon dioxide
photocatalytic reduction
graphite phase carbon nitride
tungsten trioxide
Z-scheme photocatalyst
catalysis technology
