摘要
以糠醛渣为原料,通过氯化镍浸渍和氯化锌活化制备了糠醛渣衍生的磁性多孔炭。结果表明,制备的多孔炭不仅具有磁性,还含有丰富的官能团和多孔结构;当浸渍后原料与氯化锌的质量比为1∶2时,比表面积达1051 m^(2)/g,45℃下对亚甲基蓝的吸附量可达732.5 mg/g,且吸附过程符合准二级动力学方程和Langmuir等温吸附模型。
The magnetic porous carbon was prepared using furfural residue as raw material by impregnation with nickel chloride and activation with zinc chloride.The results showed that the prepared porous carbon was magnetic with rich functional groups and many pores.When the mass ratio of raw material after impregnation to zinc chloride was 1∶2,the specific surface area could reach 1051 m^(2)/g.The adsorption capaci-ty of methylene blue could be as high as 732.5 mg/g at 45℃,and the adsorption process conformed to the pseudo second-order kinetic and Langmuir isothermal adsorption models.
作者
汪奇
张欣
姜炜坤
王孝辉
刘玉
王慧梅
WANG Qi;ZHANG Xin;JIANG Weikun;WANG Xiaohui;LIU Yu;WANG Huimei(State Key Lab of Biobased Material and Green Papermaking,Qilu University of Technology(Shandong Academy of Sciences),Ji’nan,Shandong Province,250353;Shandong Huatai Paper Group Co.,Ltd.,Dongying,Shandong Province,257000;Shandong Yellow Triangle Biotechnology Industry Research Co.,Ltd.,Dongying,Shandong Province,257000)
出处
《中国造纸学报》
CAS
CSCD
北大核心
2024年第1期155-162,共8页
Transactions of China Pulp and Paper
基金
齐鲁工业大学(山东省科学院)揭榜制(2022JBZ01-05)
齐鲁工业大学(山东省科学院)科教产融合试点工程基础研究类项目(2023PX107)
中国博士后面上基金项目(2022M711230)。
关键词
糠醛渣
多孔炭
亚甲基蓝
吸附性能
furfural residue
porous carbon
methylene blue
adsorption property