摘要
6-CH_(3)PyCH_(2)CH(2-BrC_(6)H_(4))OH与Ru_(3)(CO)_(12)在四氢呋喃中加热回流反应,得到双配体三核钌羰基簇合物[6-CH_(3)PyCH_(2)CH(2-BrC_(6)H_(4))O]_(2)Ru_(3)(CO)_(8).通过元素分析、红外光谱(IR)、核磁共振波谱(NMR)以及单晶X-射线衍射(SXRD)对簇合物的元素组成和结构进行了表征.结果表明,簇合物分子式为C_(36)H_(26)Br_(2)N_(2)O_(10)Ru_(3),属于单斜晶系,P2_(1)/c空间群,CCDC号为1907702.
By reacting 6-CH_(3)PyCH_(2)CH(2-BrC_(6)H_(4))OH with Ru_(3)(CO)_(12)under heating reflux in tetrahydrofuran,the dual ligand trinuclear ruthenium carbonyl cluster compound[6-CH_(3)PyCH_(2)CH(2-BrC_(6)H_(4))O]_(2)Ru_(3)(CO)_(8)was synthesized.The elementary composition and structure of the cluster compound was characterized by elemental analysis,infrared spectrum(IR),nuclear magnetic resonance spectroscopy(NMR)and single crystal X-ray diffraction(SXRD).The results showed that the molecular formula of the cluster compound was C_(36)H_(26)Br_(2)N_(2)O_(10)Ru_(3),belonging to monoclinic crystal system with space group P2_(1)/c.And the CCDC number is 1907702.
作者
许慧
岳晓辉
郝志强
韩占刚
林进
XU Hui;YUE Xiaohui;HAO Zhiqiang;HAN Zhangang;LIN Jin(College of Chemistry and Materials Science,Hebei Normal University,National Experimental Chemistry Teaching Center,Hebei Key Laboratory of Organic Functional Molecules,Hebei Shiiazhuang 050024,China)
出处
《河北师范大学学报（自然科学版）》
CAS
2024年第4期376-380,共5页
Journal of Hebei Normal University：Natural Science
基金
河北省自然科学基金(B2021205007)
河北省教育厅科学研究项目(ZD2022110)。
关键词
6-甲基吡啶醇
羰基钌
簇合物
合成
结构
6-methylpyridinol
ruthenium carbonyl
cluster compound
synthesis
structure
