摘要
In this work,Daylily Stalks derived N doped carbon material(N-DSC)with a high specific surface area was firstly prepared by a chemical activation method,and then cubic Cu_(2)O nanoparticles were combined with the prepared N-DSC to obtain N-DSC/Cu_(2)O composite as the catalyst for the photocatalytic degradation of tetracycline(TC)antibiotics under visible light.It is found that the obtained composite had higher photocatalytic activity than pure Cu_(2)O.Particularly,25 wt%N-DSC/Cu_(2)O composite showed the highest photocatalytic performance with 95%of TC degradation within 100 min and more excellent stability.Combined with various characterizations,it is confirmed that carbon bonds should be conducive to the separation of photoelectron and hole,and the carbon layer with an excellent electrical conductivity on Cu_(2)O can reduce the charge transfer resistance between N-DSC and Cu_(2)O,thereby improving the absorption of visible light and enhancing the photocatalytic activity.Moreover,it is considered that the synergistic effect of photo-generated electron pair in Cu_(2)O and N-DSC could promote the photodegradation efficiency of N-DSC/Cu_(2)O composite.In addition,the active species capture experiment confirmed that·OH and·O_(2)should be the main active species for TC degradation under visible light.This study is expected to provide a novel low-cost photocatalysts for pollutants removal.
基金
supported by the National Natural Science Foundation of China(21908135)
the Natural Science Foundation of Shanxi Province,China(201901D111308,201901D211435,201801D221057)
PhD Research Startup Foundation of Shanxi Datong University(2018-B-01,2020-B-02)
Postgraduate education Innovation Project of Shanxi Datong University(21CX22,22CX17)
Shanxi Province innovation and entrepreneurship training program for college students(20220807,2016172).
