期刊文献+

高能机械球磨引导的纳米TiO_2晶格畸变和高压相 被引量:9

Lattice Distortion and the High Pressure Phase in Nanoparticles TiO_2 Induced by High Energy Mechanical Milling
下载PDF
导出
摘要 发现正交结构的高压相β-TiO2可通过高能球磨锐钛矿TiO2而得到。高能机械球磨减小了颗粒尺寸,球磨40h后,发现样品存在2nm~4nm的类点状颗粒和10nm~35nm的类花瓣状颗粒。高能球磨改变了锐钛矿TiO2晶粒的晶格常数。该晶格畸变现象可能与晶界区行为相关。红外吸收峰随球磨而先“蓝移”后“红移”。该“蓝移”与“红移”与晶格常数a的变化紧密相关。另外发现随着球磨时间增长,TiO2的光催化效果变差。 The orthorhombic high pressure-phase beta-TiO2 is formed through the high energy ball- milling of C5 TiO2. High energy mechanical milling decreases the particles size such that after 40 h the sample is reduced to 2nm to 4 nm dot-shaped particles and 10nm to 35nm petal-shape particles. The lattice constants of C5 TiO2 are changed by the high energy milling. Such phenomenon of lattice distortion may be connected with the behavior of grain boundaries. For the infrared absorption spectra of the milled TiO2 The ' blue shift' occurs at the beginning of balling milling. Soon after, with increasing ball milling time, the 'red shift' appears. Such 'blue shift' and 'red shift' are found to be closely related with the variation of the lattice constant a. Results also indicated that the photo - catalyst efficiency of TiO2 becomes poor with increasing ball milling time.
机构地区 山东大学
出处 《稀有金属材料与工程》 SCIE EI CAS CSCD 北大核心 2003年第1期5-8,共4页 Rare Metal Materials and Engineering
基金 教育部跨世纪优秀人才培养计划项目 高等学校骨干教师资助计划项目
关键词 机械球磨 纳米材料 晶格畸变 高压相 二氧化钛 光催化 mechanical milling nanometer materials lattice distortion high pressure - phase
  • 相关文献

参考文献7

  • 1[1]Sukharev V, Wold A, Gao Y M et al. Photoassisted Decomposition of Salicylic Acid on TiO2 and Pd/TiO2 Film [J]. J Solid State Chem, 1995, 119:339
  • 2[2]Birkefeld L D, Azad A M, Akbar S A. Carbon Monoxide and Hydrogen Detection by Anatase Modification of Titanium Dioxide [J].J Am Ceram Soc, 1992, 75:2 964
  • 3[3]Pouilleau J, Devilliers D, Groult H et al. Surface Study of a Titanium- based Ceramic Clectrode Material by X- ray Photoelectron Spectroscopy [J]. J Mater Sci, 1997, 32:5 645
  • 4[4]Hoffmann M R, Martin S T,Choi W et al. Environmental Application of Semiconductor Photocatalysis [J]. Chem Rev, 1995, 95:69
  • 5[5]Shen T D, Koch C C , Wang K Y et al. Solid- state Reaction in Nanocrystalline Fe/SiC Composites Prepared by Mechanical Alloying [J]. J Mater Sci, 1995, 32:3 835
  • 6[6]Cho Y S, Koch C C. Amorphization by Mechanical Attrition in the Nb- Ge System:Extension of the Amorphous Composition Range [J]. Mater Sci Eng A, 1993, 161:65
  • 7[7]Jia D C, Zhou Y, Lei T C. Microstructure and Mechanical Properties of Al- 12Ti- 6Nb Prepared by Mechanical Alloying [J]. Mater Sci Eng A, 1997, 232:183

同被引文献113

引证文献9

二级引证文献50

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部