摘要
1,4,8,11,15,18,22,25-octabutoxy phthalocyanine nickel(Ⅱ) was synthesized by refluxing 3,6-dibutoxy phthalonitrite with anhydrous nickel chloride in n-amyl alcohol solvent in the presence of 1,8-diazabicycloundec-7-ene(DBU).The product was characterized by elemental analysis.IR,UV-Vis and fluorescence emission spectra.The thermal stability was studied by TG and TDG.The redox potentials was measured using cyclic voltammetry(CV).
1,4,8,11,15,18,22,25-octabutoxy phthalocyanine nickel(Ⅱ) was synthesized by refluxing 3,6-dibutoxy phthalonitrite with anhydrous nickel chloride in n-amyl alcohol solvent in the presence of 1,8-diazabicycloundec-7-ene(DBU).The product was characterized by elemental analysis.IR,UV-Vis and fluorescence emission spectra.The thermal stability was studied by TG and TDG.The redox potentials was measured using cyclic voltammetry(CV).
出处
《化学研究与应用》
CAS
CSCD
北大核心
2003年第1期75-77,57,共4页
Chemical Research and Application
基金
国家自然科学基金资助项目(29871008)
关键词
丁氧基
酞菁镍(Ⅱ)
合成
结构表征
butyloxy phthalocyaninato nickel(Ⅱ)
synthesis
structure characterization
