摘要
用三氯硫磷与β-羟基乙胺类化合物在四氢呋喃溶液中反应,再加入苯酚(胺),一锅反应合成了一系列2-取代苯氧(氨)基-1,3,2-氧氮磷杂环戊烷,并对其波谱性质进行了讨论.
Using THF as the solvent,a series of new 2-substituted phenoxyl(anilino)-1,3,2-ox-azaphospholidine derivatives were prepared by the reaction of phosphorus sulfochloride with ami-noethanol directly and then treating with phenol or aniline in the presence of triethylamine.This is one pot reaction without the separation and purification of any intermediate and a high yield was obtained.AH of these compounds were confirmed by 1H NMR,IR,MS and elementary analysis,Their 1H NMR,and MS spectra and biological activity are discussed.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
1992年第8期1063-1066,共4页
Chemical Journal of Chinese Universities
基金
国家自然科学基金
关键词
氧氮磷杂
环戊烷
三氯硫磷
合成
1,3,2-Oxazaphosphoiidine,Phosphorus sulfochloride,β-Hydroxyethylamine
