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Effect of Surface Decarburization on Corrosion Behavior of GH3535 Alloy in Molten Fluoride Salts

Effect of Surface Decarburization on Corrosion Behavior of GH3535 Alloy in Molten Fluoride Salts
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摘要 Corrosion test of a Ni–16Mo–7Cr alloy with a decarburized layer was conducted in FLiNaK salt at 700 °C. A detailed microstructure study was performed to investigate the corrosion behavior and mechanisms. The results show that the Ferich layers were formed on the corroded alloys with and without decarburization. The surface decarburization had little influence on the corrosion resistance of the alloy, whereas it caused more M_2C carbide formation beneath the corrosion layer. That is attributed to the higher concentration of C gradient near the alloy surface, which was resulted from the increase in C content liberated from graphite crucible wall during the corrosion process. Corrosion test of a Ni–16Mo–7Cr alloy with a decarburized layer was conducted in FLiNaK salt at 700 °C. A detailed microstructure study was performed to investigate the corrosion behavior and mechanisms. The results show that the Ferich layers were formed on the corroded alloys with and without decarburization. The surface decarburization had little influence on the corrosion resistance of the alloy, whereas it caused more M_2C carbide formation beneath the corrosion layer. That is attributed to the higher concentration of C gradient near the alloy surface, which was resulted from the increase in C content liberated from graphite crucible wall during the corrosion process.
出处 《Acta Metallurgica Sinica(English Letters)》 SCIE EI CAS CSCD 2019年第3期401-412,共12页 金属学报(英文版)
基金 supported financially by the National Natural Science Foundation of China (Nos. 51601214, 51674237 and 11705264) the National Key Research and Development Program (No. 2017YFA0402803)
关键词 MOLTEN SALT Corrosion NI-BASED SUPERALLOYS DECARBURIZATION Molten salt Corrosion Ni-based superalloys Decarburization
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