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氮杂杯〔4〕芳烃化合物的合成

Synthesis of azacalix〔4〕arene derivatives
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摘要 以对叔丁基杯〔4〕芳烃为原料,对其上沿的叔丁基进行修饰,经不同的合成路线,利用羟基保护、取代、去叔丁基、硝化以及还原合成了尚未报道的新型氮杂杯〔4〕芳烃衍生物。其结构经1 H NMR,13C NMR和GC-MS表征。 The target compounds azacalix〔4〕arene which has not been reported,were synthesized using calix〔4〕arene as starting material by several steps reaction including hydroxyl protection,substitution,retro-Friedel-Crafts,nitration and reduction.The structure of these compounds were characterized by 1 HNMR,13 CNMR and GC-MS.The results showed that these compounds exhibited good complex effects with some heavy metals.
机构地区 同济大学化学系
出处 《精细与专用化学品》 CAS 2015年第2期30-31,共2页 Fine and Specialty Chemicals
关键词 杯〔4〕芳烃 氮杂杯〔4〕芳烃 合成 calix〔4〕arene azacalix〔4〕arene synthesis
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