摘要
By means of both a theory for pressure-induced shifts (PS) of energy spectra and a theory for shifts ofenergy spectra due to electron-phonon interaction (EPI), the 'pure electronic' PS and the PS due to EPI of R1 line ofGSGG:Cr3+ at 70 K have been calculated, respectively. Their physical origins have been revealed. It is found that theremarkable under the normal pressure, and the degree of the admixture rapidly decreases with increasing pressure. Thechange of the degree of the admixture with the pressure plays a key role for not only the pure electronic PS of R1 line butalso the PS ofR1 line due to EPL The detailed calculations and analyses show that the pressure-dependent behaviors ofthe pure electronic PS of R1 line and the PS of R1 line due to EPI are quite different. It is the combined effect of themthat gives rise to the total PS of R1 line, which has satisfactorily explained the experimental data (including a reversal ofPS of R1 line). In contributions to PS of R1 line due to EPI at 70 K, the temperature-independent contribution is muchlarger than the temperature-dependent contribution. The former results from the interaction between the zero-pointvibration of the lattice and localized electronic state.
By means of both a theory for pressure-induced shifts (PS) of energy spectra and a theory for shifts of energy spectra due to electron-phonon interaction (EPI), the 'pure electronic' PS and the PS due to EPI of R<SUB>1</SUB> line of GSGG:Cr<SUP>3+</SUP> at 70 K have been calculated, respectively. Their physical origins have been revealed. It is found that the admixture of and base-wavefunctions in the wavefunctions of R<SUB>1</SUB> level of GSGG:Cr<SUP>3+</SUP> at 70 K is remarkable under the normal pressure, and the degree of the admixture rapidly decreases with increasing pressure. The change of the degree of the admixture with the pressure plays a key role for not only the pure electronic PS of R<SUB>1</SUB> line but also the PS of R<SUB>1</SUB> line due to EPI. The detailed calculations and analyses show that the pressure-dependent behaviors of the pure electronic PS of R<SUB>1</SUB> line and the PS of R<SUB>1</SUB> line due to EPI are quite different. It is the combined effect of them that gives rise to the total PS of R<SUB>1</SUB> line, which has satisfactorily explained the experimental data (including a reversal of PS of R<SUB>1</SUB> line). In contributions to PS of R<SUB>1</SUB> line due to EPI at 70 K, the temperature-independent contribution is much larger than the temperature-dependent contribution. The former results from the interaction between the zero-point vibration of the lattice and localized electronic state.
关键词
高压
电子-声子相互作用
旋转-轨道相互作用
可调激光晶体
high-pressure effect
spin-orbit interaction
electron-phonon interaction
d orbital
coupling between t(2)(2)(T-3(1))e(4)T(2) and t(2)(3)(2)E
tunable laser crystal
