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O,O,S-三甲基硫赶磷酸酯在甲胺磷中毒检验中的应用

POISONING OF METHAMIDOPHOS IDENTIFIED BY THE PRESENCE OF O,O,S-TRIMETHYL THIOPHOSPHATE (O,O,S-TMTP)
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摘要 利用气相色谱-质谱(GC-MS)分析了甲胺磷中毒者的检材(血,胃内容物),均检出了O,O,S-三甲基硫赶磷酸酯,确未检出过甲胺磷。研究了这一现象的原因和确定了O,O,S-三甲基硫赶磷酸酯(O,O,S-TMTP)可作为甲胺磷中毒的佐证物。 It was shown by the results of GC-MS-analysis of the testing materials (blood, contents in stomach etc) taken from persons poisoned with methamidophos that O,O,S-TMTP was found in all the samples, and no methamidophos was detected. Through a thorough study on the reason of the above phenomenon, it was confirmed that the presence of O,O,S-TMTP can be taken as a proof of methamidophos poisoning. Conditions of GC-MS determination, including the preparation of sample, were studied and described in detail.
出处 《理化检验(化学分册)》 CAS CSCD 北大核心 2003年第8期464-466,共3页 Physical Testing and Chemical Analysis(Part B:Chemical Analysis)
基金 重庆市卫生科研资助项目
关键词 O O S-三甲基硫赶磷酸酯 甲胺磷 中毒检验 农药残留 食物中毒 GC-MS determination Methamidophos Poisoning O,O,S-TMTP
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