摘要
由于Al、Mn元素在钛合金中的饱和蒸汽压远大于基体元素,因此,TC2钛合金在熔炼中主组元的挥发损失较大,尤其是Mn元素,不利于铸锭化学成分均匀性控制。本文基于活度系数计算模型和控制传质系数计算模型,从热力学角度分析了钛合金熔体中Al、Mn元素的挥发趋势,分析了TC2钛合金中各元素的分布特点,结合生产实际,通过合理控制原材料,选择合适的合金添加剂及熔炼参数等,采用真空自耗电弧炉惰性气体保护熔炼出直径为720 mm的TC2钛合金铸锭,结果表明:所熔炼的铸锭径向、轴向化学成分均匀,生产的铸锭经后续加工,所得到的产品均满足标准要求,未出现宏观偏析。
Since the saturated vapor pressure of Al and Mn element in the titanium alloys is much greater than matrix elements,so the main group element of TC2 titanium alloy lose greatly and this is caused by volatilization in melting,especially Mn element. It 's not conducive to control the chemical composition uniformity. In this paper,based on the activity coefficient model and the controlled mass transfer coefficient calculation model,there is analysis of the volatile trend Al and Mn element in the titanium melts,and analysis of the distribution of the elements in TC2 titanium alloys. In actual production,TC2 titanium alloys are melted using VAR with inert gas protection to a diameter of 720 mm with reasonable control of raw materials and selecting the appropriate alloying additives and melting parameters. The results show that: the chemical composition is uniform in the radial and axial melting ingots. The products meet the standard requirements and there is no macro segregation.
出处
《中国钛业》
2016年第2期12-18,共7页
China Titanium Industry
