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Synthesis and catalytic property of Cu-Mn-Ce/γ-Al_2O_3 complex oxide 被引量:1

Synthesis and catalytic property of Cu-Mn-Ce/γ-Al_2O_3 complex oxide
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摘要 A new type of catalytic material for purification of automobile exhaust, Cu Mn Ce O/ γ Al 2O 3, has been studied. The factors affecting its catalytic activity, such as calcination temperature and the period of calcinations and so on have been investigated. Its catalytic activity after SO 2 poisoning was determined in a fixed bed reactor by exposing the sample to the atmosphere of 160?mL/min SO 2/air. The study reveals that the catalyst has shown high catalytic activities for the conversion of NH 3 oxidation by NO after sulfate. The conversion of NO reduction over the sulfated catalyst is somewhat higher than that over the fresh catalyst except that the optimum temperature has increased about 100?℃. Also at the optimum process for the experiment, the selective catalytic oxidation of CO by NO is over 76% and the conversion of NO reduction is over 80% by NH 3. A new type of catalytic material for purification of automobile exhaust, Cu Mn Ce O/ γ Al 2O 3, has been studied. The factors affecting its catalytic activity, such as calcination temperature and the period of calcinations and so on have been investigated. Its catalytic activity after SO 2 poisoning was determined in a fixed bed reactor by exposing the sample to the atmosphere of 160?mL/min SO 2/air. The study reveals that the catalyst has shown high catalytic activities for the conversion of NH 3 oxidation by NO after sulfate. The conversion of NO reduction over the sulfated catalyst is somewhat higher than that over the fresh catalyst except that the optimum temperature has increased about 100?℃. Also at the optimum process for the experiment, the selective catalytic oxidation of CO by NO is over 76% and the conversion of NO reduction is over 80% by NH 3.
出处 《中国有色金属学会会刊:英文版》 CSCD 2002年第2期317-320,共4页 Transactions of Nonferrous Metals Society of China
关键词 材料精炼 汽车排气 催化活性 双金属氧化催化 Cu-Mn-Ce/γ-Al2O3合成氧化 催化特性 purifying material automobile exhaust catalytic activity bimetallic oxide catalyst resistance to SO 2 poisoning
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