期刊文献+

A Novel Chemical Oscillator with Tyrosine as the Substrate

A Novel Chemical Oscillator with Tyrosine as the Substrate
下载PDF
导出
摘要 A new chemical oscillating reaction system involving the manganese(II)-catalyzed reaction among potassium bromate, acetone and tyrosine in acidic medium was described in this paper. The apparent activation energy of the induction period (Ein) and that of oscillation period (Ep) were calculated, Ein=110.61KJ/mol, Ep=159.41KJ/mol. The optimum concentration of each reactant was investigated and a steady chemical oscillating system was obtained. A new chemical oscillating reaction system involving the manganese(II)-catalyzed reaction among potassium bromate, acetone and tyrosine in acidic medium was described in this paper. The apparent activation energy of the induction period (Ein) and that of oscillation period (Ep) were calculated, Ein=110.61KJ/mol, Ep=159.41KJ/mol. The optimum concentration of each reactant was investigated and a steady chemical oscillating system was obtained.
机构地区 Institute of Chemistry
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2003年第12期1281-1284,共4页 中国化学快报(英文版)
基金 sponsored by the Project of Youth Teachers Foundation of Education Ministry(3076),the Project of KJCXGC-01,NWNU National Natural Science Foundation of China(29875018)
关键词 Chemical oscillator TYROSINE SUBSTRATE mechanism. Chemical oscillator tyrosine substrate mechanism.
  • 相关文献

参考文献10

  • 1[1]T.Geest, L.F.Olsen, C.G.Steinmets, R.Larter, W.M.Shafer, J.Phys.Chem. 1993, 97, 8431.
  • 2[2]P.E.Strizhak, O.Z.Didenko, T.S.Ivashchenko, Anal.Chim.Acta,. 2001, 428, 15.
  • 3[3]Yoshihiro.Sasaki, Bull.Chem.Soc.Jpn., 1999, 72, 2607.
  • 4[4]K.B.Yatsimirskii, P.E.Strizhak, S.Ivaschenko, Talanta, 1993, 40, 1227.
  • 5[5]R.Li, Non-equilibrium Thermodynamic and Dissipation Structure Theory. Qinhua Daxue, 1986.
  • 6[6]D.L.Olson, A.Scheeline, Anal.Chim.Acta., 1990, 237, 381.
  • 7[7]R. Jiménez-Prieto, M.Silva, D. Pérez-Bendito, Analyst, 1996, 121, 563.
  • 8[8]J.Gleich, Chaos: Making a new Science. Penguin, New York, 1987.
  • 9[9]E. KOrOs, M.Orban, Zs.Nagy, J.Phys.Chem., 1973, 77, 3122.
  • 10[10]R.J. Field, E. KOrOs, R.M. Noyes, J. Am. Chem. Soc., 1972, 94 , 8649.

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部