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纳米氧化钕的制备及其催化性能的研究 被引量:21

Synthesis and Combustion Catalysis of Nanometer-sized Neodymium Oxide
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摘要 Nanometer sized neodymium oxide has been synthesized by humid solid state reaction at room temperature, and characterized by scanning electron microscope, laser light scattering and X ray diffraction. The effects of nanometer sized neodymium oxide on catalyzing thermal decomposition reaction of hexogen (cyclotrimethylenetriamine, RDX) and absorbent powder (nitrocellulose absorbed nitroglycerin, NC/NG) have been investigated by DSC method. The mechanism of these catalytic reactions has also been proposed. The experimental results show that nanometer sized neodymium oxide can catalyze the decomposition reaction of RDX and NC/NG effectively. The experimental results further suggest that nanometer sized neodymium oxide is a potentially useful combustion catalyst of nitroamine propellant. Nanometer-sized neodymium oxide has been synthesized by humid solid state reaction at room temperature, and characterized by scanning electron microscope, laser light scattering and X-ray diffraction. The effects of nanometer-sized neodymium oxide on catalyzing thermal decomposition reaction of hexogen (cyclotrimethylenetriamine, RDX) and absorbent powder (nitrocellulose absorbed nitroglycerin, NC/NG) have been investigated by DSC method. The mechanism of these catalytic reactions has also been proposed. The experimental results show that nanometer-sized neodymium oxide can catalyze the decomposition reaction of RDX and NC/NG effectively. The experimental results further suggest that nanometer-sized neodymium oxide is a potentially useful combustion catalyst of nitroamine propellant.
出处 《无机化学学报》 SCIE CAS CSCD 北大核心 2003年第6期627-630,共4页 Chinese Journal of Inorganic Chemistry
基金 高等学校骨干教师资助计划项目(No.教育育部科技司犤2000犦65号)。
关键词 纳米氧化钕 制备 催化性能 纳米粉体材料 硝胺推进剂 热分解 催化剂 室温湿固相反应 nanometer material neodymium oxide catalyst hexogen absorbent powder thermal decomposition
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